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Nonlinear dielectric effect fortert-nitrobutane andtert-butylnitrile in hexane and benzene solutions

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Abstract

A nonlinear dielectric effect, and the calculated correlation factors R p and R s are reported for binary solutions of tert-nitrobutane and tert-butylnitrile in hexane and benzene. The results are discussed in terms of the three main mechanism: association of polar molecules, fluctuations in concentration and density, and intermolecular processes due to a strong electric field. The dipolar part of the cohesion energy is also accounted for.

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Zboiński, K., Saar, A. & Wojciechowska, M. Nonlinear dielectric effect fortert-nitrobutane andtert-butylnitrile in hexane and benzene solutions. J Solution Chem 12, 519–528 (1983). https://doi.org/10.1007/BF00651702

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  • DOI: https://doi.org/10.1007/BF00651702

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