Abstract
A nonlinear dielectric effect, and the calculated correlation factors R p and R s are reported for binary solutions of tert-nitrobutane and tert-butylnitrile in hexane and benzene. The results are discussed in terms of the three main mechanism: association of polar molecules, fluctuations in concentration and density, and intermolecular processes due to a strong electric field. The dipolar part of the cohesion energy is also accounted for.
Similar content being viewed by others
References
P. Debye,Phys. Z. 36, 100, 193 (1935).
St. Kielich,Dielectric and Related Molecular Processes, M. Davies, ed., (Chem. Soc., London, 1972), pp. 192–387.
C. J. F. Böttcher,Theory of Electric Polarization, revised by C. C. van Belle, P. Bordewijk, and A. Rip, Vol. 1, (Elsevier, Amsterdam, 1973), p. 293.
J. Małecki,J. Chem. Soc. Faraday II 72, 104 (1976).
N. E. Hill, W. E. Vaugham, A. H. Price, and M. Davies,Dielectric Properties and Molecular Behavior, (Van Nostrand Reinhold, London, 1969), pp. 13–17, 441, 443.
A. Piekara and B. Piekara,C. R. Acad. Sci., Paris 203, 852, 1058 (1936); A. Piekara,Proc. Roy. Soc. A172, 360 (1939); A. PiekaraActa Phys. Polon. 10, 37, 101 (1950); A. Piekara and St. Kielich,Acta Phys. Polon. 17, 209 (1958).
J. Małecki,Acta Phys. Polon. 29, 45 (1966).
C. J. F. Böttcher,Theory of Electric Polarization, revised by C. C. van Belle, P. Bordewijk, and A. Rip, Vol. 1, (Elsevier, Amsterdam, 1973), Eq. (7.25), p. 295.
L. Onsager,J. Am. Chem. Soc. 58, 1486 (1936).
K. Zboiński,Chem. Phys. Letters 39, 336 (1976).
K. Zboiński, H. Opiola, and G. Wojciechowska,Bull. Acad. Polon. Sci. Ser. Sci. Chim. 27, 85 (1979).
K. Zboiński, H. Opiola, and L. Piekara-Sady,Chem. Phys. 40, 77 (1979).
M. Konecki, Doctoral Thesis, University of Warsaw, 1980.
G. Bałakeir, Doctoral Thesis, University of Warsaw, 1981.
K. Zboiński, Doctoral Thesis, University of Warsaw, 1974.
Ref. 1,—, p. 328. 193 (1935). Fig. 16
J. Małecki,Acta Phys. Polon. 21, 13 (1962).
A. Chełkowski,Dielectric Physics, (Elsevier, Amsterdam, 1980). pp. 319, 320.
N. Kornblum and R. J. Clutter,J. Am. Chem. Soc. 76, 4494 (1954).
M. Davies,J. Chem. Phys. 63, 67 (1966).
Ref. 3,— p. 178. Eq (5.67)
Landoldt-Bornstein, 3 Teil,Molekeln II, (Springer, Berlin 1951.)
Ref. 5,—, pp. 339, 441, 443.
A. Saum,J. Polymer Sci. 42, 57 (1960).
V. P. Sazonov,Zh. Strukt. Khim. 14, 554 (1973).
P. A. D. de Maine, M. M. de Maine, and A. G. Goble,Trans. Faraday Soc. 53, 427 (1957).
W. Danhauser and A. F. Flueckinger,J. Phys. Chem. 68, 1814 (1964).
K. R. Srinivasan and R. L. Kay,J. Solution Chem. 6, 357 (1977).
B. Kasprowicz-Kielich, St. Kielich,Acta Phys. Polon. A 50, 215 (1976).
W. Pyzuk and K. Zboiński,Chem. Phys. Letters 52, 577 (1977).
J. Goulon, J. L. Greffe, and D. W. Oxtoby,J. Chem. Phys. 70, 4742 (1979).
K. Zboiński and A. Saar, to be published.
C. J. F. Böttcher,Theory of Electric Polarization, revised by C. C. van Belle, P. Bordewijk, and A. Rip, Vol. 1, (Elsevier, Amsterdam, 1973), Eqs. (4.118) and (4.120), p. 153–157.
J. Liszi,Acta Chim. Acad. Sci. Hung. 98, 73 (1978).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zboiński, K., Saar, A. & Wojciechowska, M. Nonlinear dielectric effect fortert-nitrobutane andtert-butylnitrile in hexane and benzene solutions. J Solution Chem 12, 519–528 (1983). https://doi.org/10.1007/BF00651702
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00651702