Abstract
Enthalpies of mixing ΔH m of aqueous solutions of CdCl2, CuCl2, and ZnCl2 with MgCl2 solutions were measured at ionic strengths of 1.0, 2.0, and 3.0 at 25°C. The excess enthalpy equations of Pitzer were then fitted to the resulting ΔH m data. The resulting parameters are the temperature derivatives of the activity coefficient mixing parameters in the Pitzer system.
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Schreiber, D.R., DeVon Andres & Huebner, J. Thermodynamic properties of transition metals in aqueous solution:4. The enthalpies of mixing aqueous solutions of CdCl2, CuCl2 and ZnCl2 with MgCl2 at varying ionic strength at 25°C. J Solution Chem 22, 1109–1117 (1993). https://doi.org/10.1007/BF00651693
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DOI: https://doi.org/10.1007/BF00651693