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Vapor-liquid equilibrium data at 25°C for six binary systems containing methyl acetate or methanol, with dichloromethane, chloroform, or 1,2-trans-dichloroethylene

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Abstract

Isothermal vapor-liquid equilibrium (VLE) data, at 25° C were determined by a saturation method for each of the six methanol or methyl acetate binary systems with dichloromethane, chloroform, and 1,2-trans-dichloroethylene. The experimental data satisfy the Redlich-Kister consistency test, and were correlated with five Gibbs free energy models. All the binary mixtures of methanol with the chlorinated compounds exhibit strong positive deviations from ideality while the mixtures of methyl acetate with the chlorinated compounds present negative deviations from ideal behavior.

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Authors and Affiliations

  1. Departamento de Ingeniería Química, Universidad de Valladolid, Prado de la Magdalena, s/n, 47011, Valladolid, Spain

    F. Mato

Authors
  1. Maria C. Martin
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  2. Maria J. Cocero
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  3. F. Mato
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Additional information

Communicated at the Festsymposium celebrating Dr. Henry V. Kehiaian's 60th birthday, Clermont-Ferrand, France, 17–18 May 1990.

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Martin, M.C., Cocero, M.J. & Mato, F. Vapor-liquid equilibrium data at 25°C for six binary systems containing methyl acetate or methanol, with dichloromethane, chloroform, or 1,2-trans-dichloroethylene. J Solution Chem 20, 87–95 (1991). https://doi.org/10.1007/BF00651642

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  • DOI: https://doi.org/10.1007/BF00651642

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