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Prediction of ternary excess enthalpy data by the UNIFAC Group Contribution method

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Abstract

The UNIFAC Group Contribution method is applied to predict ternary excess enthalpies HE. In order to improve previous predictions, values for the group interaction parameters are determined from binary excess enthalpy data. These parameters are used to estimate sixty-four sets of ternary HE data which are compared with data from the literature. Results are also compared with those obtained using methods to predict ternary excess enthalpies from the binary HE data for the three binary system involved.

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Authors and Affiliations

  1. Department Química Física I, Universidad Complutense, E-28040, Madrid, Spain

    B. Coto, C. Pando & J. A. R. Renuncio

  2. Department Química Física y Analítica, Universidad de Oviedo, E-33070, Oviedo, Spain

    J. A. G. Calzón

Authors
  1. B. Coto
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  2. J. A. G. Calzón
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  3. C. Pando
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  4. J. A. R. Renuncio
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Communicated at the Festsymposium celebrating Dr. Henry V. Kehiaian's 60th birthday, Clermont-Ferrand, France, 17–18 May 1990.

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Coto, B., Calzón, J.A.G., Pando, C. et al. Prediction of ternary excess enthalpy data by the UNIFAC Group Contribution method. J Solution Chem 20, 71–86 (1991). https://doi.org/10.1007/BF00651641

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  • DOI: https://doi.org/10.1007/BF00651641

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