Abstract
A recently developed model for 1-alkanol+alkane mixtures is extended to methanol mixtures and to the non-polar mixing partners tetrachloromethane and benzene. The model contains chemical and physical terms, which are combined in a thermodynamically consistent way. For our calculations on methanol mixtures, we have measured gE of methanol+ hexane via static vapor pressure measurements. In order to check the model predictions for systems with higher alkanols and alkanes, we have also determined gE of 1-octanol+tetradecane by measuring the melting curve. The reproduction of the excess properties of methanol+hexane, the agreement between predicted and measured values of gE for 1-octanol+ tetradecane, and the capability to deal also with other non-polar mixing partners demonstrate the power and reliability of the model.
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Communicated at the Festsymposium celebrating Dr. Henry V. Kehiaian's 60th birthday, Clermont-Ferrand, France, 17–18 May 1990.
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Liu, A., Pusicha, K., Demiriz, A.M. et al. Model for alkanol + alkane mixtures: Extension and experimental verification. J Solution Chem 20, 39–56 (1991). https://doi.org/10.1007/BF00651639
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DOI: https://doi.org/10.1007/BF00651639