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The interaction between sodium carboxymethylcellulose and water

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Abstract

A differential scanning calorimeter has been used to study the nonfreezing of water in a series of solutions of sodium carboxymethylcellulose. In particular, the effects of molecular weight, degree of substitution, and particle size have been investigated. The results show that large amounts of water are associated with all the samples of sodium carboxymethylcellulose, suggesting a multilayer arrangement of water molecules about the solute. A change in degree of substitution has some effect on the hydration, but it appears less significant than a change in molecular weight.

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References

  1. M. J. Tait, A. Suggett, F. Franks, S. Ablett, and P. A. Quickenden,J. Solution Chem. 1, 131 (1972).

    Google Scholar 

  2. M. A. Kabayama and D. Patterson,Can. J. Chem. 36, 563 (1958).

    Google Scholar 

  3. A. B. Biswas, C. A. Kumsah, G. Pass, and G. O. Phillips,J. Solution Chem. 4, 581 (1975).

    Google Scholar 

  4. G. N. Ling, inWater and Aqueous Solutions, R. A. Horne, ed. (Wiley, New York, 1972), p. 663.

    Google Scholar 

  5. M. M. Breuer and M. G. Kennerley,J. Colloid Interface Sci. 37, 124 (1971).

    Google Scholar 

  6. A. Suggett, inWater, a Comprehensive Treatise, F. Franks, ed. (Plenum, New York, 1975), Vol. 4, p. 519.

    Google Scholar 

  7. T. Nishiuchi,J. Chem. Soc. Jpn., Ind. Chem. Sec. 70, 345 (1967).

    Google Scholar 

  8. D. J. Stevens and G. A. H. Elton,Staerke 23, 8 (1971).

    Google Scholar 

  9. I. Kuntz, T. S. Brassfield, G. D. Law, and G. V. Purcell,Science 163, 1329 (1969).

    Google Scholar 

  10. G. N. Ling, inWater and Aqueous Solutions, R. A. Horne, ed. (Wiley, New York, 1972), p. 684.

    Google Scholar 

  11. R. M. Fuoss and G. I. Cathers,J. Polym. Sci. 4, 97 (1949).

    Google Scholar 

  12. M. Glicksman,Gum Technology in the Food Industry, (Academic Press, New York, 1969), p. 413.

    Google Scholar 

  13. A. J. Ganz,Manuf. Confect. 46, 23 (1966),

    Google Scholar 

  14. G. A. Towle, inIndustrial Gums, R. L. Whistler, ed. (Academic Press, New York, 1973), p. 100.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Chemistry and Applied Chemistry, University of Salford, M5 4WT, Salford, Lancashire, England

    C. A. Kumsah, G. Pass & G. O. Phillips

Authors
  1. C. A. Kumsah
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  2. G. Pass
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  3. G. O. Phillips
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Kumsah, C.A., Pass, G. & Phillips, G.O. The interaction between sodium carboxymethylcellulose and water. J Solution Chem 5, 799–806 (1976). https://doi.org/10.1007/BF00651490

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  • DOI: https://doi.org/10.1007/BF00651490

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