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A Raman study of the lonization of thiocyanic acid

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Abstract

Raman spectra of mixtures of hydrochloric acid and ammonium thiocyanate have been determined and separated by means of a curve resolver into contributions due to the thiocyanate ion and the thiocyanic acid molecule. By this meanspKa for the latter species is found to be −1.1±0.3 in aqueous solution at 20°C.

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Covington, A.K., Matheson, R.A. A Raman study of the lonization of thiocyanic acid. J Solution Chem 5, 781–786 (1976). https://doi.org/10.1007/BF00651488

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  • DOI: https://doi.org/10.1007/BF00651488

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