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Enthalpies of dilution of electrolyte solutions by flow microcalorimetry

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Abstract

The enthalpies of dilution of NaCl, Me4NBr, andn-Bu4NBr were measured in water at 25°C with a new flow microcalorimeter. The data were analyzed with a polynomial equation, and the derived relative apparent molal enthalpies φL are in good agreement with literature values. Provided care is taken that mixing is complete, flow calorimeters are as reliable and much less time-consuming than cell-type instruments for enthalpies of dilution measurements.

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Authors and Affiliations

  1. Department of Chemistry, Université de Sherbrooke, Sherbrooke, Québec, Canada

    J. -L. Fortier, P. -A. Leduc, P. Picker & J. E. Desnoyers

Authors
  1. J. -L. Fortier
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  2. P. -A. Leduc
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  3. P. Picker
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  4. J. E. Desnoyers
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Fortier, J.L., Leduc, P.A., Picker, P. et al. Enthalpies of dilution of electrolyte solutions by flow microcalorimetry. J Solution Chem 2, 467–475 (1973). https://doi.org/10.1007/BF00651008

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  • DOI: https://doi.org/10.1007/BF00651008

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