Abstract
Several methods for the calculation of activity coefficients for binary mixed electrolytes are compared. Their accuracies are analysed and the reasons for the different degrees of accuracies are given.
Similar content being viewed by others
References
H. L. Friedman,Ionic Solution Theory (Wiley, New York, 1962); H. L. Friedman,A Course in Statistical Mechanics (Prentice-Hall, New Jersey, 1985); H. L. Friedman,J. Chem. Phys. 32, 1134 (1960).
H. L. Friedman and C. V. Krishnan,J. Phys. Chem. 78, 1929 (1974).
T. K. Lim, E. C. Zhong, and H. L. Friedman,J. Phys. Chem. 90, 144 (1986).
H. A. C. McKay,Trans. Faraday Soc. 51, 903 (1955);Discuss. Faraday Soc. 24, 76 (1957).
T. K. Lim,J. Chem. Soc. Faraday Trans. I 81, 1195 (1985).
T. K. Lim,J. Chem. Soc. Faraday Trans. I 82, 69 (1986).
G. Scatchard,J. Am. Chem. Soc. 83, 2636 (1961);90, 3124 (1968).
G. Scatchard,Chem. Rev. 19, 309 (1939).
G. Scatchard, R. M. Rush, and J. S. Johnson,J. Phys. Chem. 74, 3786 (1970).
K. S. Pitzer,J. Phys. Chem. 77, 268 (1973).
K. S. Pitzer,J. Solution Chem. 4, 249 (1975).
K. S. Pitzer,Activity Coefficients in Electrolyte Solutions, K. S. Pitzer, ed., (CRC Press, Boca Raton, Florida, 1991).
K. S. Pitzer and J. J. Kim,J. Am. Chem. Soc. 96, 5701 (1974).
C. E. Harvie and J. H. Weare,Geochim. Cosmochim. Acta 44, 981 (1980).
T. K. Lim, C. Y. Chan, and K. H. Khoo,J. Solution Chem. 9, 507 (1980).
T. K. Lim,Int. J. Quantum. Chem. S16, 247 (1982).
T. K. Lim,J. Solution Chem. 16, 11 (1987).
T. K. Lim,J. Solution Chem. 16, 917 (1987).
T. K. Lim,J. Solution Chem. 21, 121 (1992).
H. L. Friedman,J. Solution Chem. 9, 525 (1980).
T. K. Lim,J. Chem. Soc. Faraday Trans. I 86, 3897 (1990).
T. K. Lim, submitted for publication.
K. H. Khoo, C. Y. Chan, and T. K. Lim,J. Solution Chem. 6, 651, 855 (1977).
K. H. Khoo, C. Y. Chan, and T. K. Lim,J. Chem. Soc. Faraday Trans. I 74, 837 (1978).
K. H. Khoo, T. K. Lim, and C. Y. Chan,J. Chem. Soc. Faraday Trans. I 74, 2037 (1978).
K. H. Khoo, T. K. Lim, and C. Y. Chan,J. Solution Chem. 7, 291 (1978).
T. K. Lim, K. H. Khoo, and C. Y. Chan,J. Solution Chem. 9, 785 (1980).
R. G. Bates and R. A. Robinson,J. Solution Chem. 9, 455 (1980).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lim, TK., Khoo, SK., Hernandez-Luis, F. et al. Comparative studies of calculation methods for activity coefficients of unsymmetrical mixed electrolytes. J Solution Chem 21, 963–970 (1992). https://doi.org/10.1007/BF00650872
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00650872