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Prediction of vapor-liquid equilibrium from excess enthalpy data for binary ether +n-alkane or cyclohexane mixtures

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Abstract

Vapor liquid equilibrium (VLE) is successfully predicted from excess enthalpy HE data for binary ether + n-alkane or cyclohexane mixtures. Parameters for the continuous linear association model (CLAM) and for the UNIQUAC Model for the excess Gibbs energy GE were determined from HE data measured at a low temperature (ambient temperature). These parameters are used to predict VLE data at low and high temperatures. The dependence of the accuracy of predictions on the set of HE data chosen to evaluate the parameters and on the model for GE are discussed.

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References

  1. J. J. Christensen, R. W. Hanks, and R. M. Izatt,Handbook of Heats of Mixing (Wiley, New York, 1982).

    Google Scholar 

  2. J. J. Christensen, R. L. Rowley, and R. M. Izatt,Handbook of Heats of Mixing, Supplementary Volume (Wiley, New York, 1988).

    Google Scholar 

  3. R. W. Hanks, A. C. Gupta, and J. J. Christensen,I. and E. C. Fundam. 10, 504 (1971).

    Google Scholar 

  4. J. M. Prausnitz, T. F. Anderson, E. A. Grens, C. A. Eckert, R. Hsich, and J. P. O'Connell,Computer Calculations for Multicomponent Vapor-Liquid and Liquid-Liquid Equilibria (Prentice Hall, Englewood Cliffs, NJ, 1980).

    Google Scholar 

  5. J. M. Prausnitz, R. N. Lichtenthaler, and E. Gomes de Azevedo,Molecular Thermodynamics of Fluid-Phase Equilibria, 2nd edn., (Prentice Hall, Englewood Cliffs, NJ, 1986).

    Google Scholar 

  6. C. Pando, J. A. R. Renuncio, R. W. Hanks, and J. J. Christensen,Thermochim. Acta 63, 173 (1983).

    Google Scholar 

  7. J. A. G. Calzón, C. Pando, and J. A. R. Renuncio,Thermochim. Acta 106, 219 (1986).

    Google Scholar 

  8. R. W. Hanks, T. K. O'Neill, and J. J. Christensen,I. and E. C. Process. Des. Dev. 18, 408 (1979).

    Google Scholar 

  9. C. Pando, J. A. R. Renuncio, R. W. Hanks, and J. J. Christensen,Thermochim. Acta 62, 113 (1983).

    Google Scholar 

  10. C. Pando, J. A. R. Renuncio, R. W. Hanks, and J. J. Christensen,I. and E. C. Process. Des. Dev. 23, 73 (1984).

    Google Scholar 

  11. J. A. G. Calzón, C. Pando, J. A. R. Renuncio, and J. J. Christensen,Thermochim. Acta 91, 37 (1985).

    Google Scholar 

  12. H. Renon and J. M. Prausnitz,Chem. Eng. Sci. 22, 299 (1967);Errata 22, 1891 (1967).

    Google Scholar 

  13. R. H. Pennington,Introductory Computer Methods and Numerical Analysis, 2nd edn., (Macmillan, London, 1970).

    Google Scholar 

  14. R. G. Rubio, J. A. R. Renuncio, and M. Díaz Peña,Fluid Phase Equilib. 12, 217 (1983).

    Google Scholar 

  15. G. M. Wilson,Adv. Cryog. Eng. 9, 168 (1964);11, 392 (1966); 65th Natl. Meeting AIChE, 4–7 May, (Cleveland 1969), Paper 15C.

    Google Scholar 

  16. D. S. Abrams and J. M. Prausnitz,AIChE J. 21, 116 (1975).

    Google Scholar 

  17. B. Marongiu, S. Dernini, L. Lepori, E. Matteoli, and H. V. Kehiaian,J. Chem. Eng. Data 33, 118 (1988).

    Google Scholar 

  18. H. Arm, D. Bankay, K. Strub, and M. Wälti,Helv. Chim. Acta 50, 1013 (1964).

    Google Scholar 

  19. L. Lepori, E. Matteoli, and B. Marongiu,Fluid Phase Equilib. 42, 229 (1988).

    Google Scholar 

  20. K. Sosnkowska-Kehiaian, R. Hryniewicz, and H. V. Kehiaian,Bull. Acad. Pol. Sci. Ser. Sci. Chim. 17, 185 (1969).

    Google Scholar 

  21. T. Treszczanowicz and B. C.-Y Lu,J. Chem. Thermodyn. 18, 213 (1986).

    Google Scholar 

  22. F. Kimura, P. J. D'Arcy, and G. C. Benson,J. Chem. Thermodyn. 15, 511 (1983).

    Google Scholar 

  23. T. Treszczanowicz,Bull. Acad. Pol. Sci. Ser. Sci. Chim. 21, 107 (1973).

    Google Scholar 

  24. L. Wang, G. C. Benson, and B. C.-Y. Lu,J. Chem. Thermodyn. 20, 975 (1988).

    Google Scholar 

  25. V. C. Maripuri and G. A. Ratcliff,J. Chem. Eng. Data 17, 454 (1972).

    Google Scholar 

  26. B. Ruiz, F. M. Royo, and S. Otin,J. Chem. Thermodyn. 20, 239 (1988).

    Google Scholar 

  27. A. De Torre, I. Velasco, S. Otin, and C. Gutierrez Losa,J. Chem. Thermodyn. 12, 87 (1980).

    Google Scholar 

  28. M. Oba, S. Murakami, and R. Fujishiro,J. Chem. Thermodyn. 9, 407 (1977).

    Google Scholar 

  29. K. N. Marsh, J. B. Ott, and M. J. Costigan,J. Chem. Thermodyn. 12, 857 (1980).

    Google Scholar 

  30. G. C. Benson, B. Luo, and B. C.-Y Lu,Can. J. Chem. 66, 531 (1988).

    Google Scholar 

  31. M. A. Villamañan, C. Casanova, A. H. Roux, and J.-P. E. Grolier,J. Chem. Eng. Data 27, 89 (1982).

    Google Scholar 

  32. M. K. Kumaran and G. C. Benson,J. Chem. Thermodyn. 18, 27 (1986).

    Google Scholar 

  33. H. V. Kehiaian, K. Sosnkowska-Kehiaian, and R. Hryniewicz,J. Chim. Phys. 68, 922 (1971).

    Google Scholar 

  34. R. Meyer, G. L. Giusti, and E.-J. Vincent,Thermochim. Acta 31, 262 (1979).

    Google Scholar 

  35. G. C. Benson, M. K. Kumaran, and P. J. D'Arcy,Thermochim. Acta 74, 187 (1984).

    Google Scholar 

  36. T. Treszczanowicz and B. C.-Y Lu,J. Chem. Thermodyn. 19, 391 (1987).

    Google Scholar 

  37. T. Treszczanowicz, G. C. Benson, and B. C.-Y Lu,J. Chem. Eng. Data 33, 379 (1988).

    Google Scholar 

  38. J. K. H. Al-Kafaji and C. Booth,J. Chem. Soc. Faraday Trans. I 79, 2695 (1983).

    Google Scholar 

  39. G. C. Benson, M. K. Kumaran, T. Treszczanowicz, P. J. D'Arcy, and C. J. Halpin,Thermochim. Acta 95, 59 (1985).

    Google Scholar 

  40. J. Timmermans,Physico-Chemical Constants of Pure Organic Compounds, Vols. 1, 2 (Elsevier, Amsterdam, 1950, 1965).

    Google Scholar 

  41. R. D. Gunn and T. Yamada,AIChE J. 17, 1341 (1971).

    Google Scholar 

  42. A. Fredenslund, J. Gmehling, and P. Rasmussen,Vapor-Liquid Equilibrium Using UNIFAC (Elsevier, Amsterdam, 1977).

    Google Scholar 

  43. R. C. Reid, J. M. Prausnitz, and T. K. Sherwood,The Properties of Gases and Liquids, 3rd edn., (McGraw-Hill, New York, 1977).

    Google Scholar 

  44. K. H. Simmrock, R. Janowsky, and A. Ohnsorge,Critical Data of Pure Substances, D. Behrens and R. Eckermann (DECHEMA, Frankfurt/Main, 1986).

    Google Scholar 

  45. A. L. Lydersen, University of Wisconsin Eng. Exp. Stn. Rep., 3 (1955).

  46. W. C. Edmister,Pet. Refiner. 37, 173 (1958).

    Google Scholar 

  47. J. Gmehling and U. Onken,Vapor-Liquid Equilibrium Data Collection, Chemistry Data Series, (DECHEMA, Frankfurt/Main, 1977).

    Google Scholar 

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  1. Departamento Química-Física I, Universidad Complutense, E-28040, Madrid, Spain

    B. Coto, C. Pando & J. A. R. Renuncio

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  1. B. Coto
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  2. C. Pando
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  3. J. A. R. Renuncio
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Coto, B., Pando, C. & Renuncio, J.A.R. Prediction of vapor-liquid equilibrium from excess enthalpy data for binary ether +n-alkane or cyclohexane mixtures. J Solution Chem 21, 667–682 (1992). https://doi.org/10.1007/BF00650760

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  • DOI: https://doi.org/10.1007/BF00650760

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