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Viscosities and intradiffusion coefficients in the ternary system NaCl−MgCl2−H2O at 25°C

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Abstract

The intradiffusion coefficients of Na+, Cl ions and water and the tracerdiffusion coefficients of Ca2+ ion have been measured in the ternary system NaCl−MgCl2−H2O at 25°C. The intradiffusion coefficients of Mg2+ in this system have been estimated from the corresponding Ca2+ diffusion measurements. Viscosities were measured at the same solution concentrations as were used for the diffusion experiments. Intradiffusion and tracerdiffusion coefficients in a range of temperatures from 5 to 45°C are reported for standard sea-water which is a member of the above ternary set.

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References

  1. A. R. Altenberger and H. L. Friedman,J. Chem. Phys. 78, 4162 (1983).

    Google Scholar 

  2. C. Y. Mou, T. S. Thacher, and J. Lin,J. Chem. Phys. 79, 957 (1983).

    Google Scholar 

  3. T. S. Thacher, J. Lin, and C. Y. Mou,J. Chem. Phys. 81, 2053 (1984).

    Google Scholar 

  4. D. G. Miller, private communication, who is coordinating this study.

  5. J. F. Chambers, J. M. Stokes, and R. H. Stokes,J. Phys. Chem. 60, 985 (1956).

    Google Scholar 

  6. S. Phang and R. H. Stokes,J. Solution Chem. 9, 497 (1980).

    Google Scholar 

  7. R. Mills and L. A. Woolf,The Diaphragm Cell (ANU Press, Canberra, 1969).

    Google Scholar 

  8. K. R. Harris, R. Mills, P. J. Back and D. S. Webster,J. Magn. Resonance 29, 473 (1978).

    Google Scholar 

  9. R. Mills,J. Phys. Chem. 77, 685 (1973).

    Google Scholar 

  10. K. R. Harris, H. G. Hertz, and R. Mills,J. Chim. Phys. 75, 391 (1978).

    Google Scholar 

  11. R. Mills,J. Amer. Chem. Soc. 77, 6116 (1955).

    Google Scholar 

  12. R. A. Robinson and R. H. Stokes,Electrolyte Solutions, 2nd edn. (Butterworths, London, 1959).

    Google Scholar 

  13. J. G. Albright, R. Mathew, and L. Paduano, private communication.

  14. R. H. Stokes and R. Mills,Viscosity of Electrolytes and Related Properties, (Pergamon, Oxford, 1965).

    Google Scholar 

  15. I. J. O'Donnell and L. J. Gosting,The Structure of Electrolytic Solutions, ed. W. J. Hamer (Wiley, New York, 1959) Chap. 11, p. 160.

    Google Scholar 

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Mills, R., Easteal, A.J. & Woolf, L.A. Viscosities and intradiffusion coefficients in the ternary system NaCl−MgCl2−H2O at 25°C. J Solution Chem 16, 835–840 (1987). https://doi.org/10.1007/BF00650753

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  • DOI: https://doi.org/10.1007/BF00650753

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