Abstract
Conductance measurements are reported for Al(ClO4)3 in acetonitrile Co(ClO4)2, Zn(ClO4)2, and Al(ClO4)3 in dimethylformamide, and Al(ClO4)3, Fe(ClO4)3, and FeCl3 in dimethylsulfoxide (DMSO), at 25°C. From uv spectral effects the FeCl (DMSO) 2+5 complex cation is shown, to predominate in DMSO, while hexasolvated cations occur in the metal perchlorate solutions. The limiting conductances of the cations, including earlier data, indicate non-Stokesian dependences of mobility on the ionic charge, a unique property of the structurally related complex ions ML z+6 and MXL (z−1)+5 . The observed regularities are discussed in terms of both their possible applications and the migration mechanism.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.References
R. L. Kay, D. F. Evans, and M. Matesich inSolute-Solvent Interactions, J. F. Coetzee and C. D. Ritchie, eds. (Marcel Dekker, 1976), p. 105.
C. B. Monk,Electrolytic Dissociation, (Academic Press, London, 1961), p. 132, and references therein.
R. M. Fuoss and D. Edelson,J. Am. Chem. Soc. 73, 269 (1951).
A. Diamond, A. Fanelli, and S. Petrucci,Inorg. Chem. 12, 611 (1973).
M. Born,Z. Physic 1, 221 (1920).
R. Zwanzig,J. Chem. Phys. 38, 1603 (1963).
W. Libuś, B. Chachulski, L. Fraczyk, and H. Strzelecki,Roczniki Chem. 49, 19 (1975).
W. Libuś, M. Pilarczyk, and T. Szuchnicka,Electrochim. Acta 25, 1033 (1980).
W. Libuś, B. Chachulski, and L. Fraczyk,J. Solution Chem. 9, 355 (1980).
D. Puchalska, E. Kamienska-Piotrowicz, and W. Libuś,Electrochim. Acta. 24, 381 (1979).
J. Reedijk, W. L. Driessen, and W. L. Groeneveld,Rec. Trav. Chim. 88, 1095 (1969).
N. A. Matwiyoff,Inorg. Chem. 5, 788 (1966).
J. E. Prue and P. J. Sherrington,Trans. Faraday Soc. 57, 1975 (1961).
M. Pilarczyk and W. Libuś,Bull. Acad. Polon. Sci., Ser. Sci. Chim. 20, 539 (1972).
W. G. Movins and N. A. Matwiyoff,Inorg. Chem. 6, 847 (1967).
J. F. O'Brien and M. Alei,J. Phys. Chem. 74, 743 (1970).
Y. Ruben and J. Reuben,J. Phys. Chem. 80, 2394 (1976).
T. Shedlovsky,J. Am. Chem. Soc. 54, 1405 (1932).
A. C. Covington and T. Dickinson,Physical Chemistry of Organic Solvent Systems, (Plenum Press, London, 1973), p. 5.
M. D. Monica, D. Masciopinto, and G. Tessari,Trans. Faraday Soc. 66, 2872 (1970).
C. H. Springer, J. F. Coetzee, and R. L. Kay,J. Phys. Chem. 73, 471 (1969).
J. Quint and A. Viallard,J. Solution Chem. 7, 533 (1978), and references therein.
W. H. Lee and R. J. Wheaton,J. Phys. Chem. 82, 605 (1978).
R. S. Drago, D. M. Hart, and R. L. Carlson,J. Am. Chem. Soc. 87, 1901 (1965).
W. Libuś, W. Grzybkowski, and R. Pastewski,J. Chem. Soc. Faraday I 77, 147 (1981).
D. E. Arrington and E. Griswold,J. Phys. Chem. 74, 123 (1970).
J. Burges,Metal Ions in Solution, (Wiley, New York, 1978).
W. Libuś and H. Strzelecki,Electrochim. Acta 15, 703 (1970);16, 1749 (1971).
W. Libuś and M. Pilarczyk,Bull. Acad. Polon. Sci., Ser. Sci. Chim. 20, 539 (1972).
C. B. Baddiel, M. J. Tait, and G. J. Janz,J. Phys. Chem. 69, 3634 (1965).
H. L. Yeager and B. Kratochvil,J. Phys. Chem. 73, 1963 (1969).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Libuś, W., Chachulski, B., Grzybkowski, W. et al. Mobilities of complex forming cations in non-aqueous donor solvents. J Solution Chem 10, 631–648 (1981). https://doi.org/10.1007/BF00650739
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00650739