Journal of Solution Chemistry

, Volume 20, Issue 7, pp 693–701 | Cite as

Prediction of infinite dilution activity coefficients of sulfur dioxide in organic solvents

  • Robert J. Demyanovich
  • Scott Lynn
Article

Abstract

Infinite dilution activity coefficients of sulfur dioxide in various organic solvents were correlated with two basicity scales: the solvent Gutmann donor number and Arnett heat of hydrogen bonding. Linear correlations were observed for both basicity scales, and the accuracy of activity coefficient prediction is estimated to be ±20 to 25%. Infinite dilution activity coefficients of sulfur dioxide in over 80 organic solvents were estimated from the correlations.

Key words

Infinite dilution activity coefficient estimation organic solvent basicity scales Gutmann donor number Arnett basicity scale 

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Copyright information

© Plenum Publishing Corporation 1991

Authors and Affiliations

  • Robert J. Demyanovich
    • 1
  • Scott Lynn
    • 2
  1. 1.LiquiSheet Technologies Inc.Oakland
  2. 2.Department of Chemical EngineeringUniversity of CaliforniaBerkeley

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