Abstract
The pairwise interaction concept used by Savage and Wood to predict enthalpies of interaction of nonelectrolytes has been applied to several tetraalkylammonium bromides, triethylamine, and some trialkylphosphates in binary aqueous amide mixtures. It is possible to use the same model for electrolytes as well. Values of the functional group interaction parameters for both nonelectrolytes and electrolytes are in reasonable agreement.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
J. J. Savage and R. H. Wood,J. Solution Chem. 5, 733 (1976).
C. de Visser and G. Somsen,J. Solution Chem. 3, 847 (1974);J. Phys. Chem. 78, 1719 (1974).
C. de Visser, W. J. M. Heuvelsland, and G. Somsen,J. Solution Chem. 4, 311 (1975).
W. J. M. Heuvelsland, C. de Visser, and G. Somsen,J. Phys. Chem. 82, (1978).
W. J. M. Heuvelsland, C. de Visser, and G. Somsen, to be published.
H. L. Friedman and C. V. Krishnan,J. Solution Chem. 2, 2460 (1973).
J. E. Desnoyers, G. Perron, L. Avédikian, and J. P. Morel,J. Solution Chem. 5, 631 (1976).
S. Lindenbaum, D. Stevenson, and J. H. Rytting,J. Solution Chem. 4, 893 (1975).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
de Visser, C., Heuvelsland, W.J.M. & Somsen, G. The pairwise interaction concept of Savage and Wood applied to electrolytes. J Solution Chem 7, 193–196 (1978). https://doi.org/10.1007/BF00650526
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00650526