Journal of Solution Chemistry

, Volume 7, Issue 3, pp 137–153 | Cite as

The relaxation field for the general case of electrolyte mixtures

  • J. Quint
  • A. Viallard
Article

Abstract

The relaxation field for solutions of mixed electrolytes of any type is calculated. the calculation is based on the well-known treatment due to Fuoss-Onsager with the same distance parameter for all the ions in solution. A general conductance-continuity equation has been established and an improved iterative method of calculation, using Laplace transforms, is proposed. The relaxation-field results are derived to the second iteration in the perturbation method of integration.

Key Words

Relaxation field mixed electrolytes kinetic effect unsymmetrical electrolytes conductance theory 

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References

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    J. Quint and A. Viallard, submitted toJ. Solution Chem. (1978).Google Scholar

Copyright information

© Plenum Publishing Corporation 1978

Authors and Affiliations

  • J. Quint
    • 1
  • A. Viallard
    • 1
  1. 1.Laboratoire de Thermodynamique et Cinétique Chimique, U.E.R. des Sciences Exactes et NaturellesUniversité de Clermont-Ferrand 2AubièreFrance

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