Abstract
The base-catalyzed decomposition of nitramide in 80% dimethyl sulfoxide (DMSO)-20% water (by weight) has been investigated. The Brønsted catalysis law for a series of seven carboxylate ions in this mixed solvent is compared with the Brønsted relationship previously obtained in water. There is no real change in mechanism upon changing the solvent from pure water to this aqueous mixture, which is approximately equimolar in the two-solvent components.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.References
R. P. Bell,The Proton in Chemistry, (Chapman and Hall, London, 1973), Chapter 9, p. 160.
C. D. Ritchie, inSolute-Solvent Interactions, J. F. Coetzee and C. D. Ritchie, eds. (Marcel Dekker, New York, 1969), Chapter 4.
E. H. Baughman and M. Kreevoy,J. Phys. Chem. 78, 421 (1974).
R. Eliason and M. Kreevoy,J. Phys. Chem. 78, 2658 (1974).
A. I. Hassid, M. Kreevoy, and T. M. Laing,J. Chem. Soc. Faraday Trans. 10, 72 (1975).
E. C. Baughan and R. P. Bell,Proc. Roy. Soc. Ser. A 158, 464 (1937).
C. A. Marlies, V. K. LaMer, and J. Greenspan,Inorg. Synth. 1, 68 (1939).
S. Tellier-Pollon and J. Heubel,Rev. Chim. Miner. 4, 413 (1967).
R. P. Bell and A. F. Trotman-Dickenson,J. Chem. Soc. 1288 (1949).
R. W. Hay,Lab. Pract. 12, 752 (1963).
I. M. Kolthoff and M. K. Chantooni, Jr.,J. Am. Chem. Soc. 87, 4428 (1965).
I. M. Kolthoff and M. K. Chantooni,J. Am. Chem. Soc. 93, 3843 (1971).
N. M. Ballash, E. B. Robertson, and D. M. Sokolowski,Trans. Faraday Soc. 66, 2622 (1970).
J. C. Halle, R. Gaboriaud and R. Schaal,Bull. Soc. Chim. Fr., 2047 (1970).
B. G. Cox, P. De Maria, and A. Fini,Gaz. Chim. Ital. 106, 817 (1976).
R. A. Marcus,J. Phys. Chem. 72, 891 (1968).
R. Jones,Prog. Phys. Org. Chem. 9, 241 (1972).
B. G. Cox and A. Gibson,J. Chem. Soc. Faraday Trans. 10, 107 (1975).
K. Hiraska, R. Yaurdagni, and P. Kobarle,J. Am. Chem. Soc. 95, 6833 (1973).
R. P. Bell,Acid-Base Catalysis (Oxford University Press, London, 1941), p. 91.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
De Maria, P., Fini, A. The decomposition of nitramide in 80% dimethyl sulfoxide-20% water solvent system. J Solution Chem 6, 727–731 (1977). https://doi.org/10.1007/BF00650449
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00650449