Abstract
The enthalpies and (in part) free energies and entropies of transfer from pyridine to pyridine + diluent mixtures have been determined for MnCl2py4, Mn(NCS)2py4, Co(NCS)2py4, Ni(NCS)2py4, and NiBr2py4 complexes at 25°C using chloroform or 1,1,2,2-tetrachloroethane (TCE) as diluents. The ΔH otr data indicate specific outer-sphere interactions of the complexes with the diluents. The influence of the kind of anionic ligands and central metal ion of the complexes on their interaction with the diluents are discussed.
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References
W. Libuś, K. Chachulska, H. Inerowicz, and J. Stangret,J. Solution Chem. 14, 735 (1985).
W. Libuś, K. Chachulska, and M. Meçik,Inorg. Chem. 19, 2259 (1980).
W. Libuś, M. Kluczkowski, A. Klonkowski, and W. Nierzwicki,J. Chem. Soc. Faraday Trans. I 70, 1057 (1974);ibid 72, 2552 (1976).
W. Libuś and I. Uruska,Inorg. Chem. 5, 256 (1966).
W. Libuś, K. Chachulska, and J. Stangret,J. Solution Chem. 12, 529 (1983).
M. Meçik and W. Libuś,Bull. Acad. Polon. Sci., Ser. Sci. Chim. 24, 477 (1976).
W. Libuś, M. Meçik, and H. Strzelecki,J. Solution Chem. 9, 723 (1980).
W. Libuś, B. Janaszewski, R. Pastewski, and H. Twardowska,J. Solution Chem. 9, 737 (1980), and references therein.
W. Libuś, H. Koniarska, and H. Twardowska,Bull. Acad. Polon. Sci., Ser. Sci. Chim. 27, 529 (1979).
L. H. Jones,Inorg. Chem. 2, 777 (1963);3, 1581 (1964).
J. C. Barnes and P. Day,J. Chem. Soc. (London), 3886 (1964).
L. I. Katzin,J. Chem. Phys. 20, 1165 (1952).
E. de Valera, D. Feakins, and W. E. Waghorne,J. Chem. Soc. Faraday Trans. I 79, 1061 (1983).
B. G. Cox and W. E. Waghorne,J. Chem. Soc. Faraday Trans. I 80, 1267 (1984).
F. Becker, E. W. Fries, M. Kiefer, and H. D. Pflug,Z. Naturforsch. 25a, 677 (1970).
J. Narbutt,Bull. Acad. Polon. Sci., Ser. Sci. Chim. 22, 1095 (1974).
B. Bŀaszkiewicz and Z. Pajak,Adv. Molec. Relax. Interact. Process 13, 83 (1978), and references therein.
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Libus, W., Stangret, J., Inerowicz, H. et al. Complexes of divalent inons in mixed solvent media. II. Outer-sphere interactions in pyridine + diluent solutions. J Solution Chem 17, 337–345 (1988). https://doi.org/10.1007/BF00650414
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DOI: https://doi.org/10.1007/BF00650414