Abstract
Solvation of individual ions in ethanol are given by the sum of various contributions: electrostatic, cavity formation, interactions of ions with the solvent, and structural rearrangement of the solvent itself. An analysis of the influence of all these contributions on the temperature dependence of solvation of ions is presented.
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References
A. M. Kolker, L. P. Safonova, A. N. Kinchin, and G. A. Krestov,J. Solution Chem. 19, 975 (1990).
H. Reiss, H. L. Frisch, and J. L. Lebovitz,J. Chem. Phys. 32, 369 (1959).
H. Reiss, H. L. Frisch, and J. L. Lebovitz,J. Chem. Phys. 32, 119 (1960).
R. A. Pierotti,Chem. Rev. 76, 717 (1976).
B. A. Cosgrove and J. Walkley,Can. J. Chem. 60, 1896 (1982).
E. Wilhelm,J. Chem. Phys. 58, 3558 (1973).
A. Ben-Naim and H. L. Friedman,J. Phys. Chem. 71, 448 (1967).
L. P. Safonova, A. N. Kinchin, and A. M. Kolker,Russ. J. Phys. Chem. 63, 2919 (1989).
M. N. Abraham, J. Liszi, and L. Meszaros,J. Chem. Phys. 70, 2491 (1979).
T. Abe,J. Phys. Chem. 90, 713 (1986); S. Ehrenson,J. Phys. Chem. 7, 91, 1868 (1987).
M. Bucher and T. L. Porter,J. Phys. Chem. 90, 3406 (1986).
D. Dertolini, M. Cassettar, and G. Salvett,J. Chem. Phys. 78, 365 (1983).
M. Castagnolo, A. Sacco, and A. de Diglio,J. Chem. Soc. Faraday Trans. I 10, 2669 (1984).
R. N. French and C. M. Criss,J. Solution Chem. 11, 625 (1982).
Y. Marcus,Pure and Appl. Chem. 57, 1103 (1985).
A. M. Kolker, A. N. Kinchin, L. P. Sofanova, and S. L. Solovijov,International Conference of Chemical Thermodynamics and Calorimetry, (Beijina, China, 1989), p. A5.
V. A. Duro and T. M. Usachova,Russ. J. Phys. Chem. 56, 48 (1982).
Loewenshuss and Y. Marcus,J. Phys. and Chem. Ref. Data 16, 61 (1987).
Thermic Constants of Substances, Reference Book, Vol. 10, No. 2, Glushco, ed., (1987).
Y. Y. Ahadov,Dielectric Properties of Pure Liquid (Izd. Standartov, Moscow, 1972), p. 411.
J. Barthel, R. Wachter, and H. J. Gores,Modern Aspects of Electrochemistry, No. 13, B. E. Conway and J. M. O'Bockris, eds., (Plenum, New York, 1979), p. 1.
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Kolker, A.M., Safonova, L.P. & Kinchin, A.N. Analysis of the thermodynamic characteristics of solvation of individual ions in ethanol using model concepts. J Solution Chem 21, 533–543 (1992). https://doi.org/10.1007/BF00649562
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DOI: https://doi.org/10.1007/BF00649562