Abstract
The conductance of tetrabutylammonium tetraphenylboride, picrate, nitrate, and bromide has been measured at 25°C inn-butyronitrile and in mixtures of this solvent with dioxane, benzene, and carbon tetrachloride covering the range of dielectric constants from 10–24.26. For the picrate, nitrate, and bromide, the association constants at a given dielectric constant are independent of the chemical composition of the solvent. The changes of Walden products with solvent composition, however, are different, depending on which other solvent is mixed with the butyronitrile.
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D'Aprano, A., Fuoss, R.M. Conductance in isodielectric mixtures. I.n-butyronitrile with dioxane, benzene, and carbon tetrachloride. J Solution Chem 3, 45–55 (1974). https://doi.org/10.1007/BF00649495
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DOI: https://doi.org/10.1007/BF00649495