Abstract
The excess molar volumes of eight binary systems formed of propyl or butyl formate with four n-alkanes (from C6 to C9) have been determined at 25°C and atmospheric pressure. The data were obtained indirectly from densities measured experimentally with a vibrating-tube densimeter and then compared with those estimated using the Nitta model. This method yields good predictions of the symmetry of the vE curves given an average overall error for all the systems analyzed here smaller than 6 percent.
Similar content being viewed by others
References
T. Nitta, E. A. Turek, R. A. Greenkorn, and K. C. Chao,AIChEJ 3, 144 (1977).
A. J. Treszczanowics and G. C. Benson,Fluid Phase Equilib. 23, 117 (1985).
A. Heintz,Ber. Bunsenges. Phys. Chem. 89, 172 (1985).
G. C. Panayiotou,J. Phys. Chem. 92, 2960 (1988).
H. Funke, M. Wetzel, and A. Heintz,Pure and Appl. Chem. 61, 1429 (1989).
A. J. Treszczanowics, D. Patterson, G. C. Benson, and T. Kasprzycka-Guttman,Fluid Phase Equilib. 50, 235 (1989).
J. Ortega, J. S. Matos, M. I. Paz-Andrade, J. Fernandez, and L. Pias,Fluid Phase Equilib. 43, 295 (1988).
J. Ortega, J. S. Matos, M. I. Paz-Andrade, and J. Fernandez,J. Chem. Eng. Data 3, 464 (1987).
J. Ortega,Ber. Bunsenges. Phys. Chem. 93, 730 (1989).
F. Sarmiento, M. Lopez, M. I. Paz-Andrade, J. Fernandez, J. Ortega, and J. A. Peña,J. Chem. Thermodyn. 20, 1315 (1988).
F. Sarmiento, M. I. Paz-Andrade, G. Roux-Desgranges, and J. P. E. Grolier,Int. Data Ser., Ser. A, Sel. Data Mixtures 1, 66, 67 (1985).
F. Sarmiento, M. I. Paz-Andrade, G. Roux-Desgranges and J. P. E. Grolier,Int. Data Ser., Ser. A, Sel. Data Mixtures 1, 68, 69 (1985).
J. Ortega, J. L. Legido, J. Fernandez, M. Lopez, L. Pias, and M. I. Paz-Andrade,Fluid Phase Equilib. 56, 219 (1990).
J. A. Riddick, W. B. Bunger, and T. K. Sakano,Organic Solvents Techniques of Chemistry, Vol. II, 4th edn., (Wiley, New York, 1986).
T. E. Daubert and R. P. Danner,Data Compilations Tables of Properties of Pure Compounds (AIChE, New York, 1985).
J. Ortega, J. S. Matos, M. I. Paz-Andrade, and E. Jimenez,J. Chem. Thermodyn. 17, 1127 (1985).
J. P. E. Grolier, D. Ballet, and A. Viallard,J. Chem. Thermodyn. 6, 895 (1974).
O. Dusart, C. Piekarski, S. Piekarski, and A. Viallard,J. Chim. Phys. 73, 837 (1976).
J. P. E. Grolier and A. Viallard,J. Chim. Phys. 10, 1442 (1971).
J. S. Matos, J. Ortega, and M. V. Garcia,J. Chem. Eng. Data 33, 269 (1988).
R. Gonzalez, F. Murrieta-Guevara, and A. Trejo,J. Solution Chem. 15, 791 (1986).
J. M. Navarro, Ph.D. Thesis, (University of Santiago, 1983).
J. K. Wilmhurst,J. Mol. Spectroscopy 1, 201 (1957).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Matos, J.S., Ortega, J., Tardajos, G. et al. Analysis of volumes of mixing for propyl and butyl formate withn-alkanes in terms of the Nitta model. J Solution Chem 19, 1063–1071 (1990). https://doi.org/10.1007/BF00649451
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00649451