Abstract
Enthalpies of dilution of aqueous systems containing formamide, dimethyl-formamide, the mixture of these amides, and each amide separately with mannitol, inositol, and cyclohexanol have been determined at 25°C. The data have been treated in terms of the Savage-Wood additivity principle and in combination with literature data. New values for the methylene-amide, carbinol-amide, and amide-amide group interaction enthalpies are presented. These may be used with data on a wider variety of solute systems to obtain interaction enthalpies for new groups.
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References
J. J. Savage and R. H. Wood,J. Solution Chem 5, 733 (1976).
R. H. Wood and I. R. Tasker,J. Phys. Chem. submitted.
I. R. Tasker, R. H. Wood, and H. J. Albert. To be published.
A. L. Harris, P. T. Thompson, and R. H. Wood,J. Solution Chem. 9, 305 (1980).
R. B. Cassel and R. H. Wood,J. Phys. Chem. 78, 2465 (1974).
B. Y. Okamoto, R. H. Wood, J. E. Desnoyers, G. Perron, and L. Delorme,J. Solution Chem. 10, 139 (1981).
C. de Visser, W. J. M. Heuvelsland, and G. Somsen,J. Solution Chem. 7, 193 (1978).
G. M. Blackburn T. H. Lilley, and E. Walmsley,J. C. S. Faraday I 76, 915 (1980).
G. M. Blackburn, T. H. Lilley, and E. Walmsley,J. C. S. Chem. Comm. 1091 (1980).
F. T. Gucker, Jr., H. B. Pickard, and W. L. Ford,J. Amer. Chem. Soc. 62, 2698 (1940).
G. S. Kresheck,J. Phys. Chem. 73, 2441 (1969).
R. H. Wood and L. H. Hiltzik,J. Solution Chem. 9, 45 (1980).
This work.
H. S. Gutowsky and C. H. Holm,J. Chem. Phys. 25, 1228 (1956).
R. C. Petersen,J. Phys. Chem. 64, 184 (1960).
C. E. de Vissar, G. Perron, J. E. Desnoyers, W. J. M. Heuvelsland, and G. Somsen,J. Chem. Eng. Data 23, 74 (1977).
J. A. Schellman,C. R. Trav. Lab. Carlsberg, Ser. Chim. 29, 223 (1955).
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Tasker, I.R., Wood, R.H. Enthalpies of dilution of aqueous solutions of amides and alcohols. J Solution Chem 11, 295–308 (1982). https://doi.org/10.1007/BF00649288
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DOI: https://doi.org/10.1007/BF00649288