Abstract
It is shown that it is possible to fit conductance data in solvents of low dielectric constant without the additional assumption of triple ion formation. With the aid of two new conductance equations, which incoporate in different ways a mass action law for ion pairing but not for ion triplets, we can account for the conductivity data for the systems LiBr in octanol and NaI in butanol. One of the equations incorporates the mean spherical approximation.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
P. Beronius and T. Lindback,Acta Chem. Scand. A32, 423 (1978).
P. Beronius,Acta Chem. Scand. A32, 887 (1978).
R. M. Fuoss and C. A. Kraus,J. Am. Chem. Soc. 55, 2387 (1933).
P. Bacelon, J. Corset, and C. de Loze,J. Solution Chem. 9, 129 (1980).
P. J. Rossky, J. B. Dudowicz, B. L. Tembe, and H. L. Friedman,J. Chem. Phys. 73, 3372 (1980).
R. M. Fuoss,Z. Elektrochemie 39, 513 (1933).
G. S. Bien, C. A. Kraus, and R. M. Fuoss,J. Am. Chem. Soc. 56, 1860 (1934).
C. A. Kraus and R. M. Fuoss,J. Am. Chem. Soc. 55, 211 (1933).
A. M. Sukhotin and Z. N. Timofeeva,Zhur. Fiz. Khim. 33, 1602 (1959).
F. Luder, P. Kraus, C. A. Kraus, and R. M. Fuoss,J. Am. Chem. Soc. 58, 255 (1936).
J. Kielland,J. Am. Chem. Soc. 58, 1855 (1936).
V. K. La Mer and W. G. Parks,J. Am. Chem. Soc. 53, 2040 (1931).
C. W. Davies,Ion Association, (Butterworths, London, 1962), Chap. 10.
W. Ebeling and M. Grigo,Ann. Physik (Leipzig) 37, 21 (1980).
M Grigo, J. Einfeldt, and W. Ebeling,Wiss. Z. University of Rostock, to appear.
W. Ebeling,Z. phys. Chem. 238, 400 (1968).
H. Falkenhagen and W. Ebeling,Ionic Interactions, Vol. 1, S. Petrucci ed., (Academic Press, 1971).
D. Kremp, W.-D. Kraeft, and W. Ebeling,Ann. Physik (Leipzig) 18, 246 (1966).
W. Ebeling, W.-D. Kraeft, and D. Kremp,J. Phys. Chem. 70, 3338 (1966).
H. Falkenhagen, W. Ebeling, and W.-D. Kraeft,Ionic Interactions, Vol. 1, S. Petrucci, ed., (Academic Press, 1971).
J.-C. Justice and W. Ebeling,J. Solution Chem. 8, 809 (1979).
W. Ebeling and J. Rose,J. Solution Chem. 10, 599 (1981).
W. Ebeling and M. Grigo,J. Solution Chem. 11, 151 (1982).
R. Sandig, K. Scherwinski, and M. Grigo,Elektrolytdatenbank SAFE ‘Rostocken Phys. Manuskripte’, Wilhelm Pieck Universität, Rostock (1982).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Grigo, M. Remarks on triple ion formation. Interpretation of conductance data. J Solution Chem 11, 529–537 (1982). https://doi.org/10.1007/BF00649253
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00649253