Skip to main content
SpringerLink
Log in

Prediction of the acidity level of concentrated mineral acid mixtures

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

A method for calculating the acidity level of mixtures of concentrated acidic solutions is presented. The method is based on the concept of isoacidity and the Zdanovskii rule. The calculated acidity function Ro(H) for ternary mixtures of phosphoric, sulfuric and perchloric acid are in good agreement with the values determined experimentally by electrochemical measurements.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. V. Slack,Phosphoric Acid Vol. 1, (Marcel Dekker, New York, 1968), parts 1,2.

    Google Scholar 

  2. C. Louis. Ph.D Thesis, University of Nancy, 1983.

  3. C. Louis and J. Bessiere,Can. J. Chem. 64, 608 (1986).

    Google Scholar 

  4. C. Louis, A. Bebba and J. Bessiere,Can. J. Chem. 66, 2422, (1988).

    Google Scholar 

  5. C. Louis, a. Bebba and J. Bessiere,Can. J. Chem. 65, 1353, (1987).

    Google Scholar 

  6. A. B. Zdanovskii,Trudy Solyanoi Laboratorii Akad. Nauk. SSSR 6, 1 (1936).

    Google Scholar 

  7. H. M. Koepp, H. Wendt and H. Strehlow,Z. Electrochem. 64, 483 (1960).

    Google Scholar 

  8. H. Strehlow,The Chemistry of Non-Aqueous Solvents Vol. 1, J. J. Lagowski ed., (Academic Press, New York. 1966), p. 129.

    Google Scholar 

  9. H. Pisch and C. Pdoitrenau,Rev. Soc. Quim. Mexico 30, 152 (1986).

    Google Scholar 

  10. H. Pisch and C. Poitrenaud,Rev. Soc. Quim. Mexico 33, 86 (1989).

    Google Scholar 

  11. J. Ly and C. Poitrenaud,Analysis 14, 192 (1986).

    Google Scholar 

  12. Yu. G. Frolov,Uspekhi Khimii 50, 429, (1981).

    Google Scholar 

  13. V. M. Vdovenko and M. A. Ryazanov,Radiokhimiya 7, 442 (1965).

    Google Scholar 

  14. G. Yu. Frolov and D. A. Denisov,Zh. Fiz. Khim. 52, 1308 (1978).

    Google Scholar 

  15. V. M. Vdovenko and M. A. Ryazanov,Radiokhimiya,8, 519 (1966).

    Google Scholar 

  16. A. Bebba, Ph.D. Thesis, University of Nancy, 1987.

  17. N. Medouni, Ph.D Thesis, University of Nancy, 1991.

  18. F. Coussemant, M. Hellin and B. Torck,Les Fonctions d'Acidité et leurs Utilisations en Catalyse Acido-Basique (Gordon and Breach Paris, 1969).

    Google Scholar 

  19. C. J. O'Connor,J. Chem. Edu. 46, 686 (1969).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Chimie et d'Electrochimie Analytique, Université de Nancy I, 54506, Vandoeuvre-lès-Nancy, France

    J. Bessiere, K. Aroua & C. Louis

Authors
  1. J. Bessiere
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. Aroua
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. C. Louis
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bessiere, J., Aroua, K. & Louis, C. Prediction of the acidity level of concentrated mineral acid mixtures. J Solution Chem 22, 243–252 (1993). https://doi.org/10.1007/BF00649247

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00649247

Key Words

Search

Navigation