Journal of Solution Chemistry

, Volume 22, Issue 3, pp 211–217 | Cite as

Solubility of nonpolar gases in tetrahydrofuran at 0 to 30°C and 101.33 kPa partial pressure of gas

  • F. Gibanel
  • M. C. López
  • F. M. Royo
  • J. Santafé
  • J. S. Urieta
Article

Abstract

Solubility measurements of several nonpolar gases (He, Ne, Ar, Kr, Xe, H2, D2, N2, CH4, C2H4, C2H6, CF4 and SF6) in tetrahydrofuran from 0 to 30°C and 101.33 kPa partial pressure of gas are reported. Thermodynamic functions for the solution process (Gibbs energy, enthalpy, and entropies) at 25°C are evaluated from experimental values of gas solubility as mole fractions and their variation with temperature. Lennard-Jones 6–12 pair potential parameters for tetrahydrofuran are estimated using the scale particle theory; experimental solubilities as mole fraction are compared with values calculated using this theory.

Key Words

Gas solubilities tetrahydrofuran nonpolar gases thermodynamic functions of solution scaled particle theory 

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Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • F. Gibanel
    • 1
  • M. C. López
    • 1
  • F. M. Royo
    • 1
  • J. Santafé
    • 1
  • J. S. Urieta
    • 1
  1. 1.Departmento de Química Física, Facultad de CienciasCiudad UniversitariaZaragozaSpain

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