Journal of Solution Chemistry

, Volume 16, Issue 8, pp 605–613 | Cite as

The use of gas chromatography to study solubility in polymeric systems

  • G. J. Price
  • J. E. Guillet
Article

Abstract

Since the first use of GLC in 1969 to study the thermodynamics of polymer solutions, a wide range of properties has been investigated. A brief description of the method is presented and measurements of solubility, Henry's Law constants, activity coefficients and solubility parameters for a number of solvents in poly(dimethyl siloxane), polyisobutylene and ethylene-propylene rubber at 25°C are given to illustrate the method.

Key words

Polymer solution gas chromatography interaction parameter Henry's constant activity coefficient solubility parameter polydimethyl siloxane poly isobutylene 

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References

  1. 1.
    D. C. Bonner,J. Macromol. Sci., Rev. Macromol. Chem. C13, 263 (1975).Google Scholar
  2. 2.
    A. J. Ashworth and G. J. Price,Thermochim. Acta 82, 161 (1984).Google Scholar
  3. 3.
    O. Smidsrod and J. E. Guillet,Macromolecules 2, 272 (1969). J. E. Guillet,J. Macromol. Sci. Chem. A4, 1669 (1970); J. E. Guillet,New Developments in Gas Chromatography, H. Purnell, ed., (Wiley, New York, 1973).Google Scholar
  4. 4.
    J. E. G. Lipson and J. E. Guillet,Developments in Polymer Characterization-3, J. V. Dawkins, ed., (Applied Science, Barking, 1982), p. 3.Google Scholar
  5. 5.
    J. R. Conder and J. H. Purnell,Trans. Faraday Soc. 64, 1505, 3100 (1968).Google Scholar
  6. 6.
    J. R. Conder and J. H. Purnell,Trans Faraday Soc. 65, 824, 829 (1969).Google Scholar
  7. 7.
    N. F. Brockmeier, R. W. McCoy, and J. A. Meyer,Macromolecules 5, 130, 464 (1972).Google Scholar
  8. 8.
    G. J. Price and J. E. Guillet,J. Macromol. Sci. Chem., in press.Google Scholar
  9. 9.
    G. J. Price and J. E. Guillet,J. Chromatography, in press.Google Scholar
  10. 10.
    J. R. Conder and C. L. Young,Physicochemical Measurement by Gas Chromatography, (Wiley, Chichester, 1978).Google Scholar
  11. 11.
    J.-M. Braun and J. E. Guillet,Macromolecules 8, 557 (1975).Google Scholar
  12. 12.
    R. N. Lichtenthaler, D. D. Liu, and J. M. Prausnitz,Macromolecules 7, 565 (1974).Google Scholar
  13. 13.
    D. Patterson, Y. B. Tewari, H. P. Schreiber, and J. E. Guillet,Macromolecules 4, 356 (1971).Google Scholar
  14. 14.
    J. H. Dymon and E. B. Smith,The Virial Coefficients of Pure Gasses and Their Mixtures, (Clarendon Press, Oxford, 1969).Google Scholar
  15. 15.
    T. Boublik, V. Fried, and E. Hala,The Vapour Pressure of Pure Substances, (Elsevier, New York, 1973).Google Scholar
  16. 16.
    Selected Values of the Properties of Hydrocarbons, API Project 44.Google Scholar
  17. 17.
    Selected Values of the Properties of Chemical Compounds, TRC Data Project, College Station, 1965.Google Scholar
  18. 18.
    R. D. Newman and J. M. Prausnitz,AIChE J. 19, 704 (1973).Google Scholar
  19. 19.
    G. DiPaola-Baranyi and J. E. Guillet,Macromolecules 11, 228 (1978).Google Scholar
  20. 20.
    J. Bandrup and E. H. Immergut, eds.,Polymer Handbook, (Wiley, New York, 1975).Google Scholar
  21. 21.
    P. J. Flory,Disc. Faraday Soc. 49, 7 (1970).Google Scholar

Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • G. J. Price
    • 1
  • J. E. Guillet
    • 2
  1. 1.Dept. of ChemistryThe City UniversityLondon
  2. 2.Department of ChemistryUniversity of TorontoTorontoCanada

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