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Solubility of 13 nonpolar gases in deuterium oxide at 15–45°C and 101.325 kPa. Thermodynamics of transfer of nonpolar gases from H2O to D2O

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Abstract

Using a computer controlled version of the Ben-Naim and Baer apparatus, the solubilities of He, Ne, Ar, Kr, H2, D2, N2, O2, CH4, C2H6, C3H8, CF4, and SF6 in D2O (and the solubility of CF4 in H2O) were determined at four temperatures in the range 288 to 318 K and at a partial pressure of gas of 101.325 kPa. The precision of the measurements was 0.3–1.0%. The experimental data were processed using rigorous thermodynamic methods and were fitted to the Clarke-Glew-Weiss equation. Changes in the thermodynamic properties on solution were calculated from the smoothing equations. Scaled-particle theory (SPT) was used to determine the Lennard-Jones (6,12) pair potential parameters for D2O: σ=0.275 nm and ε/k=83.4 K. Experimental mole fraction solubilities and thermodynamic functions at 298.15 K were compared with results calculated using the SPT. The thermodynamic transfer functions of gases from H2O to D2O were calculated. The changes induced by the solvation process on the structure of water were estimated from the Gibbs energy of transfer and the difference in the hydrogen bond energies for D2O and H2O.

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References

  1. H. S. Frank and W. M. Evans,J. Chem. Phys. 13, 507 (1945).

    Google Scholar 

  2. E. M. Arnett and D. R. McKelvey, inSolute-Solvent Interactions, J. F. Coetzee and C. D. Ritchie, eds., (Marcel Dekker, New York, 1969), Ch. 6.

    Google Scholar 

  3. C. G. Swain and E. R. Thornton,J. Am. Chem. Soc. 84, 822 (1962).

    Google Scholar 

  4. C. G. Kresheck, H. Schneider, and H. A. Scheraga,J. Phys. Chem. 69, 3231 (1965).

    Google Scholar 

  5. A. Ben-Naim,J. Chem. Phys. 42, 1512 (1965).

    Google Scholar 

  6. D. B. Dahlberg,J. Phys. Chem. 76, 2045 (1972).

    Google Scholar 

  7. A. Ben-Naim, J. Wilf, and M. Yaacobi,J. Phys. Chem. 77, 95 (1973).

    Google Scholar 

  8. C. Jolicoeur and G. Lacroix,Can. J. Chem. 51, 3051 (1973).

    Google Scholar 

  9. A. Vesala,Acta Chem. Scand. A 28, 839 (1974).

    Google Scholar 

  10. A. Ben-Naim,J. Phys. Chem. 79, 1268 (1975).

    Google Scholar 

  11. A. Ben-Naim and Y. Marcus,J. Chem. Phys. 81, 2016 (1984).

    Google Scholar 

  12. A. Ben-Naim and Y. Marcus,J. Chem. Phys. 83, 4744 (1985).

    Google Scholar 

  13. A. Ben-Naim,Solvation Thermodynamics (Plenum Press, New York, 1987), p. 75.

    Google Scholar 

  14. D. D. Eley,Trans. Faraday Soc. 35, 1281, 1421 (1939).

    Google Scholar 

  15. D. D. Eley,Trans. Faraday Soc. 40, 184 (1944).

    Google Scholar 

  16. G. Némethy and H. A. Scheraga,J. Chem. Phys. 36, 401 (1963).

    Google Scholar 

  17. D. N. Glew,J. Phys. Chem. 66, 605 (1962).

    Google Scholar 

  18. A. Ben-Naim,J. Phys. Chem. 69, 1922, 3240, 3245 (1965).

    Google Scholar 

  19. E. Wilhelm and R. Battino,J. Chem. Phys. 56, 563 (1972).

    Google Scholar 

  20. E. Wilhelm, R. Battino, and R. J. Wilcock,Chem. Rev. 77, 219 (1977).

    Google Scholar 

  21. IUPAC Solubility Data Series, Vol. 1,Helium and Neon, H. L. Clever, ed. (Pergamon, New York, 1978), pp. 2 and 125.

    Google Scholar 

  22. IUPAC Solubility Data Series, Vol. 2,Krypton, Xenon and Radon, H. L. Clever, ed., (Pergamon, New York, 1978), p. 2.

    Google Scholar 

  23. IUPAC Solubility Data Series, Vol. 4,Argon, H. L. Clever, ed., (Pergamon, New York, 1979), p. 2.

    Google Scholar 

  24. IUPAC Solubility Data Series, Vol. 5/6,Hydrogen and Deuterium, C. L. Young, ed., (Pergamon, New York, 1981), pp. 2 and 279.

    Google Scholar 

  25. IUPAC Solubility Data Series, Vol. 7,Oxygen and Ozone, R. Battino, ed., (Pergamon, New York, 1981), p. 2.

    Google Scholar 

  26. IUPAC Solubility Data Series, Vol. 9,Ethane, W. Hayduk, ed., (Pergamon, New York, 1982), p. 1.

    Google Scholar 

  27. IUPAC Solubility Data Series, Vol. 10,Nitrogen and Air, R. Battino, ed., (Pergamon, New York, 1982), p. 2.

    Google Scholar 

  28. IUPAC Solubility Data Series, Vol. 24,Propane, Butane and 2-Methylpropane, W. Hayduk, ed., (Pergamon, New York, 1986), p. 2.

    Google Scholar 

  29. IUPAC Solubility Data Series, Vol. 27/28,Methane, H. L. Clever and C. L. Young, eds., (Pergamon, New York, 1987), p. 3.

    Google Scholar 

  30. H. Reiss, H. L. Frisch, E. Helfand, and J. L. Lebowitz,J. Chem. Phys. 32, 119, (1960).

    Google Scholar 

  31. H. Reiss,Adv. Chem. Phys. 9, 1 (1965).

    Google Scholar 

  32. R. A. Pierotti,J. Phys. Chem. 69, 281 (1965).

    Google Scholar 

  33. R. A. Pierotti,J. Chem. Phys. 67, 1840 (1963).

    Google Scholar 

  34. R. A. Pierotti,Chem. Rev. 76, 717 (1976).

    Google Scholar 

  35. E. Wilhelm and R. Battino,J. Chem. Thermodyn. 3, 379 (1971).

    Google Scholar 

  36. E. Wilhelm and R. Battino,J. Chem. Phys. 55, 4012 (1971).

    Google Scholar 

  37. E. Wilhelm and R. Battino,J. Chem. Phys. 56, 563 (1972).

    Google Scholar 

  38. E. Wilhelm,J. Chem. Phys. 58, 3558 (1973).

    Google Scholar 

  39. A. Ben-Naim and H. L. Friedman,J. Phys. Chem. 71, 448 (1967).

    Google Scholar 

  40. F. H. Stillinger,J. Solution Chem. 2, 141 (1973).

    Google Scholar 

  41. A. Ben-Naim and S. Baer,Trans. Faraday Soc. 59, 2735 (1963).

    Google Scholar 

  42. T. Tominaga, R. Battino, H. K. Gorowara, R. D. Dixon, and E. Wilhelm,J. Chem. Eng. Data 31, 175 (1986).

    Google Scholar 

  43. R. Battino, M. Banzhof, M. Bogan, and E. Wilhelm,Anal. Chem. 43, 806 (1971).

    Google Scholar 

  44. R. Battino and H. L. Clever,Chem. Rev. 66, 395 (1966).

    Google Scholar 

  45. E. Wilhelm and R. Battino,Chem. Rev. 73, 1 (1973).

    Google Scholar 

  46. H. L. Clever and R. Battino, inSolutions and Solubilities, Techniques of Chemistry Series, Vol. 8, Part 1, M. R. J. Dack, ed., (Wiley, New York, 1975), p. 379.

    Google Scholar 

  47. E. Wilhelm,CRC Rev. Anal. Chem. 16, 129 (1985).

    Google Scholar 

  48. W. Ostwald,Solutions (Longmans, London, 1891), p. 1.

    Google Scholar 

  49. R. Battino,Fluid Phase Equilib. 15, 231 (1984).

    Google Scholar 

  50. V. K. Abrosimov, A. N. Strakhov, and G. A. Krestov,Izv. Vyssh. Ucheb. Zaved., Khim. Tekhnol. 17, 1463 (1974).

    Google Scholar 

  51. R. Crovetto, R. Fernandez-Prini, and M. L. Japas,J. Chem. Phys. 76, 1077 (1982).

    Google Scholar 

  52. B. A. Cosgrove and J. Walkley,J. Chromatogr. 216, 161 (1981).

    Google Scholar 

  53. A. N. Strakhov, S. G. Kudryatsev, and G. A. Krestov,Zh. Fiz. Khim. 58, 1801 (1984).

    Google Scholar 

  54. W.-Y. Wen and J. A. Muccitelli,J. Solution Chem. 8, 225 (1979).

    Google Scholar 

  55. E. C. W. Clarke and D. N. Glew,Trans. Faraday Soc. 62, 539 (1966).

    Google Scholar 

  56. R. F. Weiss,Deep-Sea Res. 17, 721 (1970).

    Google Scholar 

  57. M. A. Gallardo, M. C. Lopez, J. S. Urieta, and C. Gutierrez Losa,Fluid Phase Equilib. 50, 223 (1989).

    Google Scholar 

  58. M. C. Lopez, M. A. Gallardo, and J. S. Urieta,J. Chem. Eng. Data 35, 60 (1990).

    Google Scholar 

  59. G. S. Kell,J. Chem. Eng. Data 12, 66 (1967).

    Google Scholar 

  60. L. Monchick and E. A. Mason,J. Chem. Phys. 35, 1676 (1961).

    Google Scholar 

  61. R. Fernandez-Prini, R. Crovetto, M. L. Japas, and D. Laria,Acc. Chem. Res. 18, 207 (1985).

    Google Scholar 

  62. S. F. Dec and S. J. Gill,J. Solution Chem. 14, 827 (1985).

    Google Scholar 

  63. G. Olofsson, A. A. Oshodi, E. Qvarnström, and I. Wadsö,J. Chem. Thermodyn. 16, 1041 (1984).

    Google Scholar 

  64. J. H. Hildebrand, J. M. Prausnitz, and R. L. Scott,Regular and Related Solutions. The Solubility of Gases, Liquids and Solids (Van Nostrand Reinhold, New York, 1970), p. 138.

    Google Scholar 

  65. S. J. Gill and I. Wadsö,J. Chem. Thermodyn. 14, 905 (1982).

    Google Scholar 

  66. S. F. Dec and S. J. Gill,Rev. Sci. Instrum. 55, 765 (1984).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, University of Turku, SF-20500, Turku, Finland

    Pirketta Scharlin

  2. Department of Chemistry, Wright State University, 45435, Dayton, OH

    Rubin Battino

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  1. Pirketta Scharlin
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  2. Rubin Battino
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Scharlin, P., Battino, R. Solubility of 13 nonpolar gases in deuterium oxide at 15–45°C and 101.325 kPa. Thermodynamics of transfer of nonpolar gases from H2O to D2O. J Solution Chem 21, 67–91 (1992). https://doi.org/10.1007/BF00648981

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  • DOI: https://doi.org/10.1007/BF00648981

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