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An analysis of the total ion-solvent encounter configuration of ClO −4 and BF −4 with Na+ and Li+ in water, studied by various nuclear magnetic relaxation times. Part 21

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Abstract

Proton relaxation rates of the solvent water in NaClO4, NaBF4, LiClO4, and NiBF4 solutions together with some self-diffusion coefficients are reported and interpreted in terms of structure-breaking effects.19F relaxation rates in7LiBF4 and6LiBF4 solutions in D2O have been measured, and the relaxation contribution caused by7Li+ has been evaluated to give a cation-anion model pair distribution function.7Li relaxation rates in H2O and D2O are also reported, and conclusions concerning the hydration structure of Li+ have been drawn. The strong relaxation effects caused by the ions BF −4 and ClO −4 on23Na+ and7Li+ have been subjected to a detailed analysis, and combined ion-solvent encounter configurations are presented which yield an electric field gradient strong enough to cause the observed effect.

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  1. M. Contreras

    Present address: Facultad de Ciencias, Departamento de Quimica, Universidad de Chile, Cas. 653, Santiago, Chile

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  1. Institut für Physikalische Chemie und Elektrochemie der Universität Karlsruhe, Germany

    M. Contreras & H. G. Hertz

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  1. M. Contreras
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Contreras, M., Hertz, H.G. An analysis of the total ion-solvent encounter configuration of ClO −4 and BF −4 with Na+ and Li+ in water, studied by various nuclear magnetic relaxation times. Part 21 . J Solution Chem 7, 99–136 (1978). https://doi.org/10.1007/BF00648753

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