Abstract
Conductance measurements are reported for tetraethylammonium halide and perchlorate salts in water-methanol mixtures over the complete composition range at 25° C. Limiting conductances and association constants are evaluated together with the distance parameters. The maxima in the limiting ionic Walden products are considered in some detail. Ionic association is generally weak, and the lack of reliable correlation betweenK A and the solvent dielectric properties supports the assumption of specific ion-solvent interaction.
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Tissier, M., Douhéret, G. The conductance of tetraethylammonium salts in water-methanol mixtures. J Solution Chem 7, 87–98 (1978). https://doi.org/10.1007/BF00648752
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DOI: https://doi.org/10.1007/BF00648752