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Apparent molar heat capacities and volumes of aqueous electrolytes: CaCl2, Cd(NO3)2, CoCl2, Cu(ClO4)2, Mg(ClO4)2, and NiCl2

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Abstract

We have used a flow calorimeter and a flow densimeter for measurements leading to apparent molar heat capacities and apparent molar volumes of six 2∶1 electrolytes in aqueous solution at 25°C. Results of these measurements have been used to derive apparent molar heat capacities and volumes at infinite dilution for all six electrolytes: CaCl2, Cd(NO3)2, CoCl2, Cu(ClO4)2, Mg(ClO4)2, and NiCl2.

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References

  1. P. Picker, P.-A. Leduc, P. R. Philip, and J. E. Desnoyers,J. Chem. Thermodyn. 3, 631 (1971).

    Google Scholar 

  2. G. Perron, N. Desrosiers, and J. E. Desnoyers,Can. J. Chem. 54, 2163 (1976).

    Google Scholar 

  3. J. E. Desnoyers, C. de Visser, G. Perron, and P. Picker,J. Solution. Chem. 5, 605 (1976).

    Google Scholar 

  4. P. P. Singh, E. M. Woolley, K. G. McCurdy, and L. G. Hepler,Can. J. Chem. 54, 3315 (1976).

    Google Scholar 

  5. P. P. Singh, K. G. McCurdy, E. M. Woolley, and L. G. Hepler,J. Solution Chem. 6, 327 (1977).

    Google Scholar 

  6. O. Enea, P. P. Singh, E. M. Woolley, K. G. McCurdy, and L. G. Hepler,J. Chem. Thermodyn. 9, 731 (1977).

    Google Scholar 

  7. P. P. Singh, J. J. Spitzer, R. M. McKay, K. G. McCurdy, and L. G. Hepler,Thermochim Acta, in press.

  8. A. Roux, G. M. Musbally, G. Perron, J. E. Desnoyers, P. P. Singh, E. M. Woolley, and L. G. Hepler,Can. J. Chem., in press.

  9. E. M. Woolley, personal communication (1977).

  10. L. G. Hepler, to be published.

  11. P. Picker, E. Tremblay, and C. Jolicoeur,J. Solution Chem. 3, 377 (1974).

    Google Scholar 

  12. G. Schwarzenbach and H. Flaschka,Complexometric Titrations, translated by H. M. N. H. Irving (Methuen & Co. Ltd., London, 1969).

    Google Scholar 

  13. G. Perron, J. E. Desnoyers, and F. J. Millero,Can. J. Chem. 52, 3738 (1974).

    Google Scholar 

  14. F. J. Millero, inWater and Aqueous Solutions: Structure, Thermodynamics, and Transport Processes, R. A. Horne, ed. (Wiley-Interscience, New York, 1972).

    Google Scholar 

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Author notes

  1. Prem Paul Singh

    Present address: Department of Chemistry, Punjab Agricultural University, Ludhiana, India

Authors and Affiliations

  1. Department of Chemistry, University of Lethbridge, Lethbridge, Alberta, Canada

    Jan J. Spitzer, Prem Paul Singh, Keith G. McCurdy & Loren G. Hepler

Authors
  1. Jan J. Spitzer
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  2. Prem Paul Singh
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  3. Keith G. McCurdy
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  4. Loren G. Hepler
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Spitzer, J.J., Singh, P.P., McCurdy, K.G. et al. Apparent molar heat capacities and volumes of aqueous electrolytes: CaCl2, Cd(NO3)2, CoCl2, Cu(ClO4)2, Mg(ClO4)2, and NiCl2 . J Solution Chem 7, 81–86 (1978). https://doi.org/10.1007/BF00648751

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  • DOI: https://doi.org/10.1007/BF00648751

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