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Calibration of conductance cells at various temperatures

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Abstract

Precise conductance measurements on aqueous potassium chloride solutions at 0, 10, 18, and 25°C have been made under various conditions over a concentration range 10−4<c<5×10−2 mole-dm−3, yielding the conductance equations

$$\begin{gathered} 25^\circ C:\Lambda = 149.873 - 95.01\sqrt c + 38.48c log c + 183.1c - 176.4c^{3/2} \hfill \\ 18^\circ C:\Lambda = 129.497 - 80.38\sqrt c + 32.87c log c + 154.3c - 143.0c^{3/2} \hfill \\ 10^\circ C:\Lambda = 107.359 - 64.98\sqrt c + 27.07c log c + 125.4c - 110.3c^{3/2} \hfill \\ 0^\circ C:\Lambda = 81.700 - 47.80\sqrt c + 20.60c log c + 93.8c - 79.3c^{3/2} \hfill \\ \end{gathered} $$

which are proposed for calibration of conductance cells.

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References

  1. F. Kohlrausch,Wied. Ann. Phys. 60, 315 (1897).

    Google Scholar 

  2. H. C. Parker,J. Am. Chem. Soc. 45, 2017 (1923).

    Google Scholar 

  3. P. Saulnier and J. Barthel,J. Solution Chem. 8, 847 (1979).

    Google Scholar 

  4. P. Saulnier,J. Solution Chem. 8, 835 (1979); Thèse de Doctorat ès Sciences, Strasbourg (1978).

    Google Scholar 

  5. G. Jones and C. Bradshaw,J. Am. Chem. Soc. 55, 1780 (1933).

    Google Scholar 

  6. F. Kohlrausch, L. Holborn, and H. Diesselhorst,Wied. Ann. Phys. 64, 417 (1898).

    Google Scholar 

  7. G. Jones and R. C. Josephs,J. Am. Chem. Soc. 50, 1049 (1928).

    Google Scholar 

  8. G. Jones and J. Prendergast,J. Am. Chem. Soc. 59, 731 (1937).

    Google Scholar 

  9. J. F. Lind, Jr., J. J. Zwolenik, and R. M. Fuoss,J. Am. Chem. Soc. 81, 1557 (1959).

    Google Scholar 

  10. R. M. Fuoss and K. L. Hsia,Proc. Natl. Acad. Sci. U.S.A. 57, 1550 (1967).

    Google Scholar 

  11. J.-C. Justice,J. Chim. Phys. 65, 353 (1968).

    Google Scholar 

  12. R. Sändig, R. Feistel, A. Grösch, and J. Einfeldt, cited in ref. 13.

  13. G. J. Janz and R. P. T. Tomkins,J. Electrochem. Soc. 124, 55C (1977).

    Google Scholar 

  14. R. Wachter and J. Barthel,Ber. Bunsenges. Phys. Chem. 83, 634 (1979).

    Google Scholar 

  15. R. Wachter and J. Barthel,Electrochim. Acta 16, 713 (1971).

    Google Scholar 

  16. J. Barthel,Ionen in nicht-wäßrigen Lösungen, Dr. Dietrich Steinkopff-Verlag, Darmstadt (1976).

    Google Scholar 

  17. G. Jones and S. K. Talley,J. Am. Chem. Soc. 55, 624 (1933).

    Google Scholar 

  18. R. Wachter, Habilitationsschrift, Regensburg (1973); H. Hammer, Diplomarbeit, Saarbrücken (1970).

  19. International Practical Temperature Scale of 1968,Metrologica 5, 35 (1969).

    Google Scholar 

  20. J. Barthel, R. Wachter, and H. J. Gores inModern Aspects of Electrochemistry, B. E. Conway and J. O'M. Bockis, eds., Vol. 13 (Plenum Press, New York, 1979).

    Google Scholar 

  21. R. L. Kay, G. A. Vidulich, and K. S. Pribadi,J. Phys. Chem. 73, 445 (1969).

    Google Scholar 

  22. M. S. Chen, Ph.D. Thesis, Yale University (1969).

  23. R. A. Robinson and R. H. Stokes,Electrolyte Solutions, 2nd edn. (Butterworth, London, 1970).

    Google Scholar 

  24. International Critical Tables, Vol. III, E. W. Washburn, ed. (McGraw-Hill, New York, 1928), pp. 25–26.

    Google Scholar 

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Barthel, J., Feuerlein, F., Neueder, R. et al. Calibration of conductance cells at various temperatures. J Solution Chem 9, 209–219 (1980). https://doi.org/10.1007/BF00648327

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