Abstract
Recalculations of the Gurney free-energy parameters Aij based on the cosphereoverlap model of Friedman and co-workers have been made using more recent experimental data. Our procedure for calculation seems to be more systematic than those previously reported. The excess energy, entropy, and volume parameters (Eij, TSij, and Vij) were also recalculated for some aqueous tetraalkylammonium halides. In addition, the excess-heat-capacity parameters Cij are also reported here for the first time. These data are discussed briefly in terms of the structural implications.
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Streng, W.H., Wen, WY. Calculation of Gurney parameters for aqueous tetraalkylammonium halides based on Friedman's cosphere-overlap model. J Solution Chem 3, 865–880 (1974). https://doi.org/10.1007/BF00647941
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DOI: https://doi.org/10.1007/BF00647941