Abstract
Experimental thermodynamic and transport data are presented for aqueous CuSO4 solution at 25°C from low concentrations to near saturation. Included are diffusion coefficients (Rayleigh interferometry), electrical conductances (DC method), and osmotic coefficients (isopiestic). These data and corresponding literature data are critically compared, as are literature density data. The resulting best values, together with previously compared transference number results, provide an extensive set of critically reviewed data for aqueous CuSO4. Onsager coefficientsl ij have been calculated for this salt and are compared with data for other valence types.
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Miller, D.G., Rard, J.A., Eppstein, L.B. et al. Mutual diffusion coefficients, electrical conductances, osmotic coefficients, and ionic transport coefficientsl ij for aqueous CuSO4 at 25°C. J Solution Chem 9, 467–496 (1980). https://doi.org/10.1007/BF00647737
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DOI: https://doi.org/10.1007/BF00647737