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ViscosityB-Coefficient of ammonium azide and the enthalpy of formation of the azide anion

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Abstract

Recent determination of the standard enthalpy of formation of the ammonium azide Δf H O (NH Δ N 3,c) and the assignment of the viscosity B-coefficient for the azide anion, B(N 3 ,aq), in aqueous solution enable us to estimate the standard enthalpy of formation of the gaseous azide anion, Δf H O (N −,g3 , — a thermochemical magnitude in some dispute — to be 192 kJ-mol−1.

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Jenkins, H.D.B. ViscosityB-Coefficient of ammonium azide and the enthalpy of formation of the azide anion. J Solution Chem 22, 1029–1031 (1993). https://doi.org/10.1007/BF00647726

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