Abstract
The exess volumes of mixing of dimethylsulfoxide with n-, sec- and tertbutylamine, n-pentylamine, n-hexylamine, n-heptylamine, n-octylamine and cyclohexylamine have been measured as a function of composition at 30°C by a dilatometric method. For all amines VE values are negative over the entire mole fraction range. The results are attributed to the interaction between unlike molecules.
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References
T. M. Letcher,J. Chem. Thermodyn. 4, 159 (1972).
R. Gopal, S. Agarwall, and D. K. Agarwal,J. Chem. Thermodyn. 8, 801 (1976).
J. Timmermans,Physico-Chemical Constants of Pure Organic Compounds (Elsevier, New York, 1950).
R. C. Weast,Handbook of Chemistry and Physics, 59th edn., (CRC Press, 1978.)
A. Weissberger, E. S. Proskauer, J. A. Riddick and E. E. Toops, Jr.,Organic Solvents, Vol. VII, 2nd edn., A. Weissberger, ed., (Interscience, New York, 1955).
M. V. P. Rao and P. R. Naidu,Can. J. Chem. 52, 788 (1974).
R. H. Stokes, B. Levien, and K. N. Marsh,J. Chem. Thermodyn. 2, 43 (1970).
K. N. Chapman and D. D. MacDonald,J. Chem. Thermodyn. 8, 675 (1976).
R. Phillippe, C. Jambon, and P. Claechet,J. Chem. Thermodyn. 5, 431 (1973).
R. J. Fort and W. R. Moore,Trans. Faraday Soc. 61, 2102 (1965).
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Rao, P.S., Subha, M.C.S. & Swamy, G.N. Excess thermodynamic properties of binary liquid mixtures containing dimethylsulfoxide at 30°C. J Solution Chem 22, 483–487 (1993). https://doi.org/10.1007/BF00647684
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DOI: https://doi.org/10.1007/BF00647684