Abstract
The heat of dilution of aqueous solutions of ZnCl2 and the heats of mixing ΔH m of aqueous solutions of CdCl2, NiCl2, and ZnCl2 with NaCl solutions were measured at 25°C. The heats of mixing were made at constant ionic strengths of 0.5, 1.0, and 3.0 molal. The excess enthalpy equations of Pitzer were then fitted to the resulting heats of dilution and heats of mixing data. The resulting parameters are the temperature derivatives of the activity coefficient mixing parameters in the Pitzer system.
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D. R. Schreiber and L. C. Schreiber,J. Solution Chem. 21, 249 (1992).
D. R. Schreiber, J. Huebner, S. Rhamani, and F. J. Millero,J. Solution Chem. 22, 201 (1993).
A. J. Ellis and I. M. McFadden,Geochim. Cosmochim. Acta 36, 413 (1972).
F. J. Millero,Pure Applied Chem. 57, 1015 (1985).
D. J. Turner, inThermodynamics of Aqueous Systems with Industrial Applications, S. A. Newman, ed., (Am. Chem. Soc., Washington, D. C., 1980), p. 653.
A. M. Rowe and J. C. S. Chou,J. Chem. Eng. Data 15, 61 (1970).
R. C. Wilhoit, inThermodynamics of Aqueous Systems with Industrial Applications, S. A. Newman, ed., (Am. Chem. Soc., Washington, D. C., 1980), p. 467.
F. J. Millero,Proc. of the First International Symposium on Hydrothermal Reactions, Gakujutsu Bunken Fukju-Kai (Assoc. for Science Documents Information, 1983), p. 111.
K. S. Pitzer,J. Phys. Chem. 77, 268 (1973).
K. S. Pitzer, inActivity Coefficients in Electrolyte Solutions (CRC Press, Boca Raton, FL, 1979), p. 157.
C. E. Harvey and J. H. Weare,Geochim. Cosmochim. Acta 44, 981 (1980).
R. T. Pabalon and K. S. Pitzer,Geochim. Cosmochim. Acta 51, 2429 (1987).
A. L. Lehninger,Biochemistry (Worth Publishing, New York, 1975).
J. R. Partington and W. E. Soper,Phil. Mag. S. 7, 209 (1929).
A. L. Robinson and W. E. Wallace,Chem. Rev. 30, 195 (1942).
H. S. Harned and B. B. Owen,The Physical Chemistry of Electrolyte Solutions (Reinhold Publishing, New York, 1958).
M. Kh. Karapet'yants, K. K. Vlasenko, A. P. Lebedeva, and S. G. Slolv'eva,Russ. J. Phys. Chem. 45, 1727 (1971).
K. K. Vlasenko and M. Kh. Karapet'yants,Russ. J. Phys. Chem. 45, 1394 (1971)
L. J. Gier and C. E. Vanderzee,J. Chem. Eng. Data 19, 315 (1974).
R. L. Berg and C. E. Vanderzee,J. Chem. Thermodyn. 7, 219 (1975).
J. J. Spitzer, P. P. Singh, K. G. McCurdy, and L. G. Hepler,J. Solution Chem. 7, 81 (1978).
J. J. Spitzer, P. P. Singh, I. V. Olofsson, and L. G. Hepler,J. Solution Chem. 7, 623 (1978).
J. J. Spitzer, I. V. Olofsson, P. P. Singh, and L. G. Hepler,J. Chem. Thermodyn. 11, 233 (1979).
A. Lo Surdo and F. J. Millero,J. Phys. Chem. 84, 710 (1980).
R. F. Pogue and G. Atkinson,J. Solution Chem. 18, 249 (1989).
G. S. Kell,J. Chem. Eng. Data 20, 97 (1975).
Handbook of Chemistry and Physics, 60th edn., R. C. Weast, ed., (CRC Press, Boca Raton, 1979).
K. S. Pitzer,J. Solution Chem. 4, 249 (1975).
L. F. Silvester and K. S. Pitzer,J. Solution Chem. 7, 327 (1978).
K. S. Pitzer,J. Phys. Chem. 87, 2360 (1983).
J. C. Peiper and K. S. Pitzer,J. Phys. Chem. 87, 2364 (1983).
R. C. Phutela and K. S. Pitzer,J. Solution Chem. 15, 649 (1986).
R. A. Robinson and R. H. Stokes,Trans. Faraday Soc. 36, 740 (1940).
J. Ananthaswamy and G. Atkinson,J. Chem. Eng. Data 30, 120 (1985).
V. K. Filippov, N. A. Charykov, and V. Rumyantsev,Dokl. Akad. Nauk. SSSR, Fiz. Khim. 296, 665 (1987);Engl. Transl. 296, 936 (1987).
R. G. Anstiss and K. S. Pitzer,J. Solution Chem. 20, 849 (1991).
H. T. Kim and W. J. Fredrick Jr.,J. Chem. Eng. Data 33, 278 (1988).
V. K. Filippov, N. A. Charykov, and V. Rumyantsev,Zhur. Neorg. Khim. 31, 1861 (1986);Engl. Transl. 31, 1071 (1986).
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Schreiber, D.R., De Von Andres, Huebner, J. et al. Thermodynamic properties of transition metals in aqueous solution: 3. The heats of mixing aqueous solutions of CdCl2, NiCl2 and ZnCl2 with NaCl at varying ionic strength at 25°C. J Solution Chem 22, 457–467 (1993). https://doi.org/10.1007/BF00647682
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DOI: https://doi.org/10.1007/BF00647682