Abstract
Water-N,N-dimethylformamide mixtures show viscosity maxima near 30 mole percent DMF at all temperatures studied, whereas the viscosity of water-formamide mixtures is an increasing monotonic function of the mole percent formamide in the mixtures. This fundamental difference in their viscosity behavior must be attributed mainly to differences in the hydrogen bonding characteristics of the two amides. In spite of this difference, the effect on the viscosity of added NaI to these two aqueous mixtures is surprisingly similar over the temperature range studied.
Similar content being viewed by others
References
S. Taniewska-Osinska and A. PiekarskaBull. Acad. Pol. Sci., ser. sci. chim. 26, 601, 613 (1978).
A. Piekarska, Z. Kozłowski, and S. Taniewska-Osinska,Acta Univ. Lodz., Folia Chimica. 24, 49 (1978).
S. Taniewska-Osinska and A. Kacperska,Pol. J. Chem. 53, 1351 (1979).
P. K. Tikoo and R. D. Singh,Electrochim. Acta 26, 1057 (1981).
Z. Kozłowski,Soc. Sci. Lodz. Acta Chim. 16, 17 (1971).
P. Assarson,J. Phys. Chem. 72, 2710 (1968).
E. W. Merry and W. S. Turner,J. Chem. Soc., London 105, 748 (1914).
P. Bruno, C. Gatti, and M. Della Monica,Electrochim. Acta. 20, 533 (1975).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Taniewska-Osinska, S., Piekarska, A. & Kacperska, A. Viscosities of NaI in water-formamide and water-N,N-dimethylformamide mixtures from 5 to 45°C. J Solution Chem 12, 717–727 (1983). https://doi.org/10.1007/BF00647383
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00647383