Skip to main content
Log in

A microcalorimetric determination of the thermodynamics of formation of the monoand bi-sulfato complexes of lanthanum in aqueous solutions between 25 and 55°C

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Using a differential microcalorimeter, the formation constants and enthalpies of formation of the mono- and bi-sulfato complexes of lanthanum ion have been evaluated for aqueous acidic solutions over a temperature range of 25 to 55°C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. Brace and E. Matijević,J. Inorg. Nucl. Chem. 35, 3691 (1971).

    Google Scholar 

  2. R. Demchak and E. Matijević,J. Colloid Interface Sci. 31, 257 (1969).

    Google Scholar 

  3. E. Matijević, R. S. Sapieszko, and J. B. Melville,J. Colloid Interface Sci. 50, 567 (1975).

    Google Scholar 

  4. B. Težak, E. Matijević, K. F. Schulz, R. Halassy, and I. Kostinčer,Proc. 2nd Intern. Congress of Surface Activity, Vol. 3, (1957) p. 607.

  5. L. J. Stryker and E. Matijević,J. Phys. Chem. 73, 1484 (1969).

    Google Scholar 

  6. C.-C. Lo, L. Meites, and E. Matijević,Anal. Chim. Acta 139, 197 (1982).

    Google Scholar 

  7. D. P. Fay and N. Purdie,J. Phys. Chem. 73, 3462 (1969).

    Google Scholar 

  8. I. M. Kolthoff,Volumetric Analysis, Vol. 3, (Interscience, New York, 1957) p. 278.

    Google Scholar 

  9. L. Meites,Crit. Rev. Anal. Chem. 8, 1 (1979).

    Google Scholar 

  10. R. G. de Carvalho and G. R. Choppin,J. Inorg. Nucl. Chem. 29, 725 (1967).

    Google Scholar 

  11. P. G. Manning,Can. J. Chem. 43, 2911 (1965).

    Google Scholar 

  12. R. M. Izatt, D. Eatough, J. J. Christensen, and C. H. Bartholomew,J. Chem. Soc. A, 47 (1969).

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Simpson, C., Matijević, E. A microcalorimetric determination of the thermodynamics of formation of the monoand bi-sulfato complexes of lanthanum in aqueous solutions between 25 and 55°C. J Solution Chem 16, 411–417 (1987). https://doi.org/10.1007/BF00647187

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00647187

Key words

Navigation