Abstract
The limiting laws for the distinct diffusion coefficient and the corresponding Onsager phenomenological coefficient are obtained from the cluster theory of electrolyte conductance. Results are given for single electrolytes and common-ion mixtures with unrestricted charges and friction coefficients in both cases.
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References
H. L. Friedman and R. Mills,J. Solution Chem. 10, 395 (1981).
R. Mills and H. G. Hertz,J. Phys. Chem. 84, 220 (1980).
L. Onsager,Ann. N.Y. Acad. Sci. 46, 241 (1945).
C. Y. Mou, T. S. Thacher, and J. L. Lin,J. Chem. Phys. 79, 957 (1983).
L. Onsager and S. K. Kim,J. Phys. Chem. 61, 215 (1957).
H. L. Friedman,J. Chem. Phys. 42, 462 (1965).
M. J. Pikal,J. Phys. Chem. 75, 3124 (1971).
T. S. Thacher, J. L. Lin, and C. Y. Mou,J. Chem. Phys. 81, 2053 (1984).
R. Saendig,Z. Phys. Chemie (Leipzig) 265, 663 (1984).
R. Sändig and R. Feistel,J. Solution Chem. 8, 411 (1979).
H. L. Friedman,Physica 30, 537 (1964).
H. L. Friedman,J. Chem. Phys. 42, 450 (1965).
R. A. Robinson and R. H. Stokes,Electrolyte Solutions, (Butterworths, London, 1955).
D. Bratko, H. L. Friedman, and E. C. Zhong,J. Chem. Phys. 85, 377 (1986).
A. R. Altenberger and H. L. Friedman,J. Chem. Phys. 78, 4162 (1983).
T. K. Lim, E. C. Zhong, and H. L. Friedman,J. Phys. Chem. 90, 144 (1986).
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Zhong, E.C., Friedman, H.L. Limiting law for distinct diffusion coefficients in ionic solutions. J Solution Chem 16, 337–346 (1987). https://doi.org/10.1007/BF00647182
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DOI: https://doi.org/10.1007/BF00647182