Journal of Solution Chemistry

, Volume 16, Issue 5, pp 337–346 | Cite as

Limiting law for distinct diffusion coefficients in ionic solutions

  • En Ci Zhong
  • Harold L. Friedman
Article

Abstract

The limiting laws for the distinct diffusion coefficient and the corresponding Onsager phenomenological coefficient are obtained from the cluster theory of electrolyte conductance. Results are given for single electrolytes and common-ion mixtures with unrestricted charges and friction coefficients in both cases.

Key words

Electrolytes diffusion limiting laws theory statistical mechanics 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    H. L. Friedman and R. Mills,J. Solution Chem. 10, 395 (1981).Google Scholar
  2. 2.
    R. Mills and H. G. Hertz,J. Phys. Chem. 84, 220 (1980).Google Scholar
  3. 3.
    L. Onsager,Ann. N.Y. Acad. Sci. 46, 241 (1945).Google Scholar
  4. 4.
    C. Y. Mou, T. S. Thacher, and J. L. Lin,J. Chem. Phys. 79, 957 (1983).Google Scholar
  5. 5.
    L. Onsager and S. K. Kim,J. Phys. Chem. 61, 215 (1957).Google Scholar
  6. 6.
    H. L. Friedman,J. Chem. Phys. 42, 462 (1965).Google Scholar
  7. 7.a)
    M. J. Pikal,J. Phys. Chem. 75, 3124 (1971).Google Scholar
  8. 7.b)
    T. S. Thacher, J. L. Lin, and C. Y. Mou,J. Chem. Phys. 81, 2053 (1984).Google Scholar
  9. 8.
    R. Saendig,Z. Phys. Chemie (Leipzig) 265, 663 (1984).Google Scholar
  10. 9.
    R. Sändig and R. Feistel,J. Solution Chem. 8, 411 (1979).Google Scholar
  11. 10.
    H. L. Friedman,Physica 30, 537 (1964).Google Scholar
  12. 11.
    H. L. Friedman,J. Chem. Phys. 42, 450 (1965).Google Scholar
  13. 12.
    R. A. Robinson and R. H. Stokes,Electrolyte Solutions, (Butterworths, London, 1955).Google Scholar
  14. 13.
    D. Bratko, H. L. Friedman, and E. C. Zhong,J. Chem. Phys. 85, 377 (1986).Google Scholar
  15. 14.
    A. R. Altenberger and H. L. Friedman,J. Chem. Phys. 78, 4162 (1983).Google Scholar
  16. 15.
    T. K. Lim, E. C. Zhong, and H. L. Friedman,J. Phys. Chem. 90, 144 (1986).Google Scholar

Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • En Ci Zhong
    • 1
  • Harold L. Friedman
    • 1
  1. 1.Department of ChemistryState University of New YorkStony Brook

Personalised recommendations