Abstract
Osmotic coefficients have been determined for three isomeric methyl glycofuranosides, viz. methyl α-D-lyxo-, α-D-ribo-, and β-D-ribofuranosides in aqueous solution by the isopiestic comparison method. The method was further applied to measure the osmotic coefficients for the ternary system consisting of calcium chloride, methyl glycofuranoside, and water. The results are analyzed in terms of an excess function from which the salting constants for the glycosides are derived. Relationships between the salting constants and the complexing of methyl glycofuranosides with calcium ion are discussed.
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Vesala, A., Käppi, R. & Lönnberg, H. Isopiestic study of the interactions between calcium chloride and methyl glycofuranosides in aqueous solution. J Solution Chem 13, 471–480 (1984). https://doi.org/10.1007/BF00647172
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DOI: https://doi.org/10.1007/BF00647172