Abstract
Enthalpies of dilution of aqueous systems containing trioxane, and trioxane with each of mannitol, inositol and cyclohexanol have been determined at 25°C. The data have been treated in terms of the Savage-Wood additivity principle and, in conjunction with literature data on ether compounds a revised estimate of the pairwise group-interaction enthalpy for CH2/−O− and a first estimate for CHOH/−O− are presented. Systems of saccharides and saccharides with alcohols do not conform to the Savage-Wood principle and an explanation in terms of the specific hydration properties of saccharides is offered.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
J. J. Savage, R. H. Wood,J. Solution Chem. 5, 733 (1976).
B. Y. Okamoto, R. H. Wood, and P. T. Thompson,J.C.S. Faraday Trans. I 74, 1990 (1978).
R. H. Wood, L. H. Hiltzik,J. Solution Chem. 9, 45 (1980).
A. L. Harris, P. T. Thompson, and R. H. Wood,J. Solution Chem. 9, 305 (1980).
C. de Visser, Heuvelsland and G. Somsen,J. Solution Chem. 7, 193 (1978).
G. M. Blackburn, T. H. Lilley, and L. Walmsley,J.C.S. Faraday Trans 1 76, 915 (1980).
G. M. Blackburn, T. H. Lilley, and L. Walmsley,J.C.S. Chem. Comm. 1091 (1980);J.C.S. Faraday Trans. I 78, 1641 (1978).
B. Y. Okamoto, R. H. Wood, J. E. Desnoyers, G. Perron, and L. Delorme,J. Solution Chem. 10, 139 (1981).
W. J. M. Heuvelsland, C. de Visser, and G. Somsen,J.C.S. Faraday Trans. I 77, 1191 (1981).
I. R. Tasker and R. H. Wood,J. Phys. Chem., submitted.
I. R. Tasker and R. H. Wood,J. Solution Chem. 11, 481 (1982).
B. M. Gesner and V. Ginsburg,Proc. Nat'l. Acad. Sci. U.S.A. 52, 750 (1964).
J.-Y. Lin, K.-Y. Tserng, C. C. Chen, L.-T. Lin, and T.-C. Tung,Nature 227, 292 (1970).
I. R. Tasker, R. H. Wood, and J. H. Albert, to be published.
R. B. Cassel and R. H. Wood,J. Phys. Chem. 78, 2465 (1974).
G. Barone, Pl Cacace, G. Castronuovo, and V. Elia,Carbohydrate Research 91, 101 (1981).
M. Mathlouthi,Carbohydrate Research 91, 113 (1981).
G. Barone, P. Cacace, G. Castronuovo, and V. Elia,Gaz. Chim. Ital. 110, 215 (1980).
G. Barone, P. Cacace, G. Castronuovo, and V. Elia,Can. J. Chem. 59, 1257 (1981).
G. Barone, P. Cacace, G. Castronuovo, and V. Elia,J.C.S. Faraday Trans. I 77, 1569 (1981).
F. Franks and M. D. Pedley,J.C.S. Faraday Trans. I 77, 1341 (1981).
J. N. Harvey and M.C.R. Symons,J. Solution Chem. 7, 571 (1978).
A. Suggett. omWater: A Comprehensive Treatise, F. Franks, ed., (Plenum Press, New York, 1975).
S. Bociek and F. Franks,J.C.S. Faraday Trans. I 75, 262 (1979).
M. A. Ryazanov,Russ. J. Phys. Chem. 53, 202 (1979).
I. R. Tasker and R. H. Wood, to be published.
G. Barone, P. Cacace, G. Castronuovo, V. Elia, and F. Iapelli,Carbohydrate Research 93, 11 (1981).
M. J. Tait, A. Suggett, F. Franks, S. Ablett, and P. A. Quickenden,J. Solution Chem. 1, 131 (1972).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Tasker, I.R., Wood, R.H. Interactions of ether groups with saccharides. Enthalpy of dilution of aqueous systems containing S-trioxane and inositol, mannitol, or cyclohexanol. J Solution Chem 11, 469–480 (1982). https://doi.org/10.1007/BF00647109
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00647109