Abstract
The osmotic coefficients of dilute aqueous solutions of [Co(pn)3]X3 [pn=1,2-diaminopropane and X=Cl−, Br− and (NO3)−] and [Co(tn)3]X3 (tn=1,3-diaminopropane and X=Cl− and Br−) have been measured from 0.00 to 0.02 mol-kg−1 at 0°C by the freezing point method. The results have been compared with those obtained from the numerical integration of the Poisson-Boltzmann equation.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. A. Castellanos, M. Caceres, and J. Nuñez,J. Chem. Eng. Data 30, 344 (1985).
J. M. Arsuaga, A. Martin, M. Caceres, and J. Nuñez,J. Chem. Eng. Data 35, 137 (1990).
I. L. Jenkins and C. B. Monk,J. Chem. Soc. 68, 73 (1951).
J. C. Bailar, Jr. and J. B. Work,J. Am. Chem. Soc. 68, 232 (1946).
R. S. Robinson and R. A. Stokes,Electrolyte Solutions (Butterworths, London, 1959).
D. G. Archer and P. Wang,J. Phys. Chem. Ref. Data 19, 371 (1990).
J. C. Rasaiah,J. Chem. Phys. 56, 3071 (1972).
J. P. Valleau and L. K. Cohen,J. Chem. Phys. 72, 5935 (1980).
F. Malatesta and T. Rotunno,Gazz. Chim. Ital. 113, 789 (1983).
F. Malatesta and T. Rotunno,Gazz. Chim. Ital. 113, 783 (1983).
L. Onsager,Chem. Rev. 13, 73 (1933).
F. Malatesta,Gazz. Chim. Ital. 109, 325 (1979).
E. A. Guggenheim and R. H. Stokes,Equilibrium Properties of Aqueous Solutions of Single Strong Electrolytes (Pergamon Press, London, 1969).
R. Zamboni, A. Giacomelli, F. Malatesta, and A. Indelli,J. Phys. Chem. 80, 1418 (1976).
B. A. Pailthorpe, D. J. Mitchell, and B. W. Ninham,J. Chem. Soc. Faraday Trans. II 80, 115 (1984).
S. Petrucci,Ionic Interactions, Vol. I (Academic Press, New York, 1971).
J. LangeZ. Physik. Chem. 168A, 147 (1934).
J. H. Jones, F. J. Spuhler, and W. A. Felsing,J. Am. Chem. Soc. 64, 965 (1942).
S. Lindenbaum and G. E. Boyd,J. Phys. Chem. 68, 911 (1964).
J. B. Macaskill and A. D. Pethybridge,J. Chem. Soc. Faraday Trans. I 71, 1465 (1975).
J. B. Macaskill and R. G. Bates,J. Solution Chem. 15, 323 (1986).
M. Yasuda,Bull. Chem. Soc. Jpn. 41, 139 (1968).
G. Wada, E. Nagao, N. Kawamura, and K. Kinumoto,Bull. Chem. Soc. Jpn. 51, 1937 (1978).
K. Kurotaki and S. Kawamura,J. Chem. Soc. Faraday Trans. I 77, 217 (1981).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Arsuaga, J.M., Caceres-Alonso, M., Baonza, V.G. et al. Osmotic coefficients of dilute aqueous solutions of unsymmetrical cobalt-amine type salts at 0°C. J Solution Chem 20, 613–621 (1991). https://doi.org/10.1007/BF00647071
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00647071