Abstract
Standard enthalpies of solution of t-BuX and CX4 (X=Cl and Br) in several alcohols are reported as measured by a calorimetric method. The corresponding transfer functions from the gas phase were calculated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. H. Abraham,Prog. Phys. Org. Chem. 11, 2 (1974);Pure & App. Chem. 57, 1055 (1985).
E. Buncel and H. Wilson,Acc. Chem. Research 12, 42 (1979).
E. M. Arnett, W. G. Bentrude, J. J. Burke, and P. McC. Duggleby,J. Am. Chem. Soc. 87, 1541 (1965).
W. Drenth and M. Cocivera,Can. J. Chem. 54, 3944 (1976).
R. M. C. Gonçalves, A. M. N. Simoes, and C. A. N. Viana,J. Chem. Soc., Perkin Trans. 2, 1923 (1984).
M. H. Abraham,J. Chem. Soc., Perkin Trans. 2, 1028 (1977).
S. Sunner and I. Wadsö,Acta Chem. Scand. 13, 97 (1959).
C. A. N. Viana, M. V. C. Campos, and R. M. C. Gonçalves,J. Chem. Soc., Faraday Trans. I 72, 1541 (1976).
R. J. Irving and I. Wadsö,Acta Chem. Scand. 18, 195 (1964).
J. O. Hill, G. Öjelund, and I. Wadsö,J. Chem. Thermodynamics 1, 111 (1969).
I. Wadsö,Science Tools 13, 33 (1966).
S. F. Dec and S. J. Gill,J. Sol. Chem. 13, 27 (1984).
R. A. Pierotti,Chem. Rev. 76, 717 (1976).
J. J. Moura Ramos, M. Lemmers, R. Ottinger, M. L. Stien, and J. Reiss,J. Chem. Research (S), 56 (1977); (M), 658 (1977).
I. Wadsö,Acta Chem. Scand. 22, 2438 (1968).
I. Wadsö,Acta Chem. Scand. 20, 536 (1966).
Handbook of Chemistry and Physics, (CRC Press, Cleveland 1973).
M. H. Abraham and G. F. Johnston,J. Chem. Soc. (A), 1610 (1971).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Gonçalves, R.M.C., Simoes, A.M.N. Enthalpies of solution oft-butyl chloride and bromide and carbon tetrachloride and tetrabromide in alcohols. J Solution Chem 16, 39–43 (1987). https://doi.org/10.1007/BF00647013
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00647013