Abstract
Association constants and the limiting molar conductances have been evaluated for Bu 4 NI in acetonitrile-toluene mixtures at 15, 25 and 35°C. The experimental data were analyzed by means of the Lee-Wheaton equation. The thermodynamic parameters for the noncoulombic interactions were evaluated.
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References
J. Barthel,Angew. Chem. (Int. Ed.) 7, 260 (1968).
M. Daggett, E. Bair, and A. Kraus,J.A.C.S. 73, 799 (1951).
G. Ritzoulis et al.,Z. Naturf. 38a, 579 (1983).
A. Pethybridge and S. Taba,J. Chem. Soc. Faraday I 76, 368 (1980).
W. Lee and R. Wheaton,J. Chem. Soc. Faraday II 74, 743 (1978).
W. Lee and R. Wheaton,J. Chem. Soc. Faraday II 74, 1456 (1978).
P. Sears, J. Caruso, and A. Popov,J. Phys. Chem. 71, 905 (1967).
G. Lester, T. Gover, and P. Sears,J. Phys. Chem. 60, 1076 (1956).
P. Sears, J. Caruso, and A. Popov,J. Phys. Chem. 71, 1756 (1967).
E. Hirsch and R. Fuoss,J.A.C.S. 82, 1018 (1960).
M. Matesich, J. Nadas, and D. Evans,J. Phys. Chem. 74, 4568 (1970).
D. Evans and P. Gardam,J. Phys. Chem. 72, 3281 (1968).
R. Kay, C. Zawoyski, and D. Evans,J. Phys. Chem. 69, 4209 (1965).
D. Evans and P. Gardam,J. Phys. Chem. 73, 158 (1969).
W. Lee and R. Wheaton,J. Chem. Soc. Faraday II 75, 1128 (1979).
R. Fuoss,J. Phys. Chem. 80, 2427 (1978).
D. Evans, C. Zayowski, and R. Kay,J. Phys. Chem. 69, 3878 (1965).
M. Kilpatric,J. Chem. Phys. 8, 306 (1940).
J. Prue,J. Chem. Educ. 46, 12 (1969).
S. Petrucci,Ionic Interactions Vol. 1, S. Petrucci, ed., (New York, 1971).
J. Barthel,Chem. Ing. Tech. 50, 259 (1978).
R. Wachter and J. Barthel,Ber. Buns. Phys. Chem. 83, 252 (1979).
R. Fuoss,J. Phys. Chem. 79, 525 (1975).
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Papadopoulos, N., Ritzoulis, G. The conductance of tetrabutylammonium lodide in toluene-acetonitrile mixtures at 15, 25, and 35°C. J Solution Chem 16, 31–37 (1987). https://doi.org/10.1007/BF00647012
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DOI: https://doi.org/10.1007/BF00647012