Abstract
In present work, a new method is developed from which activity coefficients for both electrolytes in admixture can be obtained simultaneously from the fitting of experimental activity coefficients of one of the electrolyte. The calculated results for the system HCl+KCl at 25°C are reported and discussed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
W. G. McMillan, Jr. and J. E. Mayer,J. Chem. Phys. 13, 276 (1945); J. E. Mayer,J. Chem. Phys. 18, 1426 (1950).
Harold L. Friedman,Ionic Solution Theory, (Wiley, New York, 1962).J. Chem. Phys. 32, 1134 (1960).
H. S. Harned and B. B. Owen,The Physical Chemistry of Electrolyte Solutions, 3rd edn., (Reinhold, New York, 1958).
G. Scatchard,J. Amer. Chem. Soc. 83, 2636 (1961);Chem. Rev. 19, 309 (1939).
G. Scatchard,J. Amer. Chem. Soc. 90, 3124 1968).
G. Scatchard, R. M. Rush, and J. S. Johnson,J. Phys. Chem. 74, 3786 (1970).
K. S. Pitzer,J. Phys. Chem. 77, 268 (1973).
K. S. Pitzer and J. J. Kim,J. Amer. Chem. Soc. 96, 5701 (1974).
K. S. Pitzer,J. Solution Chem. 4, 249 (1975).
H. A. C. McKay,Trans. Faraday Soc. 51, 903 (1955);Discussions Faraday Soc. 24, 76 (1957).
T. K. Lim,J. Chem. Soc. Faraday Trans. l 81, 1195 (1985);82, 69 (1986).
C. Y. Chan and K. H. Khoo,J. C. S. Faraday I 6, 1371 (1979).
H. L. Friedman,J. Solution Chem. 1, 387 (1972);ibid. 1 419 (1972).
H. L. Friedman,J. Solution Chem. 9, 525 (1980).
T. K. Lim, C. Y. Chan, and K. H. Khoo,J. Solution Chem. 9, 507 (1980).
R. A. Robinson and R. H. Stokes,Electrolyte Solutions, 2nd edn., (Butterworths, London, 1959).
K. S. Pitzer and G. Mayorga,J. Phys. Chem. 77, 2300 (1973).
R. A. Robinson,Trans. Faraday Soc. 49, 1147 (1953).
C. J. Downes,J. C. S. Faraday I 71, 425 (1975).
H. S. Harned and A. B. Gancy,J. Phys. Chem. 62, 627 (1958).
T. K. Lim, E. C. Zhong, and H. L. Friedman,J. Phys. Chem. 90, 144 (1986).
T. K. Lim,Int. J. Quantum Chem. S16, 247 (1982).
R. G. Bates and R. A. Robinson,J. Solution Chem. 9, 455 (1980).
A referee is thanked for his helpful suggestions.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lim, T.K. A new method for calculating activity coefficients of mixed electrolytes. J Solution Chem 16, 11–20 (1987). https://doi.org/10.1007/BF00647010
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00647010