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Group contributions to the thermodynamic properties of non-ionic organic solutes in dilute aqueous solution

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Abstract

The thermodynamic properties ΔG h o,ΔH h o, and ΔC p,h oassociated with the transfer of non-ionic organic compounds from gas to dilute aqueous solution and the limiting partial molar properties C op ,2 and V2 2 of these compounds in water are described through a simple scheme of group contributions. A distinction is made between groups made only of carbon and hydrogen, and functional groups i.e. groups containing at least one atom different from carbon and hydrogen. Each group is assigned a contribution, for each property, through a least squares procedure which utilizes only molecules containing at most one functional group. Finally, for compounds containing more than one functional group, correction parameters are evaluated as the differences between the experimental values and those calculated by means of the group contributions. The different behavior of hydrophilic compared with hydrophobic groups is discussed for the various properties. A rationale for the correction parameters, i.e. for the effects of the interactions among hydrophilic groups on the thermodynamic properties, is attempted.

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References

  1. J. T. Edward and P. G. Farrell,Can. J. Chem. 53, 2965 (1975).

    Google Scholar 

  2. S. Terasawa, H. Itsuki, and S. Arakawa,J. Phys. Chem. 79, 2345 (1975).

    Google Scholar 

  3. S. Cabani, G. Conti, and E. Matteoli,J. Chem. Soc., Faraday Trans. I 74, 2408 (1978).

    Google Scholar 

  4. S. Cabani and P. Gianni,J. Chem. Soc., Faraday Trans. I. 75, 1184 (1979).

    Google Scholar 

  5. J. Hine and P. K. Mookerjee,J. Org. Chem. 40, 292 (1975).

    Google Scholar 

  6. J. P. Guthrie,Can. J. Chem. 55, 3700 (1977).

    Google Scholar 

  7. S. W. Benson,Thermochemical Kinetics, 2nd ed. (John Wiley, New York, 1976).

    Google Scholar 

  8. A. Bondi,J. Phys. Chem 68, 441 (1964).

    Google Scholar 

  9. J. Traube,Samml. Chem. Vortz. 4, 255 (1899).

    Google Scholar 

  10. See Ref. 2; —.

    Google Scholar 

  11. C. V. Krishnan and H. L. Friedman inSolute-Solvent Interactions, J. F. Coetzee, and C. D. Ritchie, eds. (M. Dekker, New York, 1976), Vol. 2, Chap. 9;

    Google Scholar 

  12. M. H. Abraham,J. Am. Chem. Soc. 101, 5477 (1979),

    Google Scholar 

  13. A. Leo, C. Hansch, and P. Y. C. Jow,J. Med. Chem. 19, 611 (1976).

    Google Scholar 

  14. R. A. Pierotti,J. Phys. Chem. 69, 281 (1965);Chem. Rev. 76, 717 (1976);

    Google Scholar 

  15. M. Lucas and R. Bury,J. Phys. Chem. 80, 999 (1976);

    Google Scholar 

  16. F. Hirata and K. Arakawa,Bull. Chem. Soc. Japan. 46, 3367 (1973).

    Google Scholar 

  17. See Ref. 2; —.

    Google Scholar 

  18. N. Nichols, R. Skold, C. Spink, J. Suurkuusl, and I. Wadsö,J. Chem. Thermodyn. 8, 1081 (1976);

    Google Scholar 

  19. see Ref. 10b, —, p. 51;

    Google Scholar 

  20. C. Jolicoeur and G. Lacroix,Can. J. Chem. 54, 624 (1976);

    Google Scholar 

  21. H. Høiland and E. Vikingstad,Acta Chem. Scand. A30, 182 (1976).

    Google Scholar 

  22. S. J. Gill and I. Wadsö,Proc. Natl. Acad. Sci. USA 73, 2955 (1976).

    Google Scholar 

  23. H. S. Frank and M. W. Evans,J. Chem. Phys. 13, 507 (1945);

    Google Scholar 

  24. W. Kauzmann,Adv. Protein Chem. 14, 1 (1959);

    Google Scholar 

  25. F. Franks inMembrane Models and the Formation of Biological Membranes, L. Bolis and B. A. Pethica, eds. (North Holland Publ. Co., Amsterdam, 1969) p. 43;

    Google Scholar 

  26. M. J. Blandamer inAdv. Phys. Org. Chem., V. Gold, ed.,14 248 (1977);

  27. F. Franks inWater:A Comprehensive Treatise, F. Franks, ed. (Plenum Press, New York, 1973), Vol. 1, Chap. 1, pp. 8, 9, 13, 28; Vol. 2, Chap. 5, p. 328;

    Google Scholar 

  28. C. Tanford,The Hydrophobic Effect. Formation of Micelles and Biological Membranes, (J. Wiley, New York, 1973);

    Google Scholar 

  29. H. Devoe,J. Am. Chem. Soc. 98, 1724 (1976).

    Google Scholar 

  30. F. Shahidi and P. G. Farrell,J. Solution Chem. 7, 549 (1978).

    Google Scholar 

References

  1. A. Aihara,Bull. Chem. Soc. Japan 32, 1242 (1959).

    Google Scholar 

  2. D. M. Alexander,J. Chem. Eng. Data 4, 252 (1959).

    Google Scholar 

  3. D. M. Alexander and D. J. T. Hill,Aust. J. Chem. 22, 347 (1969).

    Google Scholar 

  4. D. M. Alexander, D. J. T. Hill, and R. L. White,Aust. J. Chem. 24, 1143 (1971).

    Google Scholar 

  5. D. Ambrose, J. H. Ellender, C. H. S. Sprake, and R. Townsend,J. Chem. Thermodyn. 7, 453 (1975).

    Google Scholar 

  6. R. J. L. Andon, J. D. Cox, and E. F. G. Herington,J. Chem. Soc. 3188 (1954).

  7. P. Arnaud, L. Avedikian, and J. P. Morel,J. Chim, Phys. 1, 45 (1972).

    Google Scholar 

  8. E. M. Arnett, W. B. Kover, and J. V. Carter,J. Am. Chem. Soc. 91, 4028 (1969).

    Google Scholar 

  9. E. M. Arnett, J. J. Burke, J. V. Carter, and C. F. Douty,J. Am. Chem. Soc. 94, 7837 (1972).

    Google Scholar 

  10. E. M. Arnett, L. E. Small, D. Oancea, and D. Johnston,J. Am. Chem. Soc. 98, 7346 (1976).

    Google Scholar 

  11. E. M. Arnett, B. Chawla, L. Bell, M. Taagepera, W. J. Hehre, and R. W. Taft,J. Am. Chem. Soc. 99, 5729 (1977).

    Google Scholar 

  12. E. M. Arnett and B. Chawla,J. Am. Chem. Soc. 101, 7141 (1979).

    Google Scholar 

  13. P. Assarsson and F. R. Eirich,J. Phys. Chem. 72, 2710 (1968).

    Google Scholar 

  14. S. W. Benson, F. R. Cruickshank, D. M. Golden, G. R. Hauger, H. E. O'Neal, A. S. Rodgers, R. Shaw, and R. Waish,Chem. Rev. 69, 279 (1969).

    Google Scholar 

  15. S. W. Benson,Thermochemical Kinetics, 2nd Ed., (Wiley, New York, 1976).

    Google Scholar 

  16. S. Bergström and G. Olofsson,J. Solution Chem. 4, 535 (1975).

    Google Scholar 

  17. L. Boje and A. Hvidt,J. Chem. Thermodyn. 3, 663 (1971).

    Google Scholar 

  18. L. Boje and A. Hvidt,Biopolymers 11, 2357 (1972).

    Google Scholar 

  19. A. Bondi,J. Phys. Chem. 68, 441 (1964).

    Google Scholar 

  20. A. Bondi,Physical Properties of Molecular Crystals, Liquids, and Gases (Wiley, New York, 1968).

    Google Scholar 

  21. O. D. Bonner and P. J. Cerutti,J. Chem. Thermodyn. 8, 105 (1976).

    Google Scholar 

  22. T. Boublik, V. Fried, and E. Hala,The Vapour Pressure of Pure Substances (Elsevier, Amsterdam, 1973).

    Google Scholar 

  23. R. S. Bradley and T. G. Cleasby,J. Chem. Soc. 1960 (1953).

  24. G. M. Brown, P. Dubreuil, F. M. Ichhaporia, and J. E. Desnoyers,Can. J. Chem. 48, 2525 (1970).

    Google Scholar 

  25. R. Bury, M. Lucas, and P. Barberi,J. Chim. Phys. 75, 575 (1978).

    Google Scholar 

  26. J. A. V. Butler, C. N. Ramchandani, and D. W. Thomson,J. Chem. Soc. 280 (1935).

  27. J. A. V. Butler and C. N. Ramchandani,J. Chem. Soc. 952 (1935).

  28. J. A. V. Butler and W. S. Reid,J. Chem. Soc. 1171 (1936).

  29. J. A. V. Butler,Trans. Faraday Soc. 33, 229 (1937).

    Google Scholar 

  30. R. G. Buttery, L. C. Ling, and D. G. Guadagni,J. Agr. Food Chem. 17, 385 (1969).

    Google Scholar 

  31. R. G. Buttery, J. L. Bomben, D. G. Guadagni, and L. C. Ling,J. Agr. Food Chem. 19, 1045 (1971).

    Google Scholar 

  32. S. Cabani, G. Conti, and L. Lepori,Trans. Faraday Soc. 67, 1933 (1971).

    Google Scholar 

  33. S. Cabani, G. Conti, and L. Lepori,Trans Faraday Soc. 67, 1943 (1971).

    Google Scholar 

  34. S. Cabani, G. Conti, and L. Lepori,J. Phys. Chem. 76, 1338 (1972).

    Google Scholar 

  35. S. Cabani, G. Conti, A. Martinelli, and E. Matteoli,J. Chem. Soc., Faraday Trans. I 69, 2112 (1973).

    Google Scholar 

  36. S. Cabani, G. Conti, and L. Lepori,J. Phys. Chem. 78, 1030 (1974).

    Google Scholar 

  37. S. Cabani, G. Conti, D. Giannessi, and L. Lepori,J. Chem. Soc., Faraday Trans. I 71, 1154 (1975).

    Google Scholar 

  38. S. Cabani, G. Conti, V. Mollica, and L. Lepori,J. Chem. Soc., Faraday Trans. I 71, 1143 (1975).

    Google Scholar 

  39. S. Cabani, G. Conti, and E. Matteoli,J. Solution Chem. 5, 125 (1976).

    Google Scholar 

  40. S. Cabani, L. Lepori, and E. Matteoli,Chim. Ind. (Milan) 58, 221 (1976).

    Google Scholar 

  41. S. Cabani, V. Mollica, L. Lepori, and S. T. Lobo,J. Phys. Chem. 81, 982 (1977).

    Google Scholar 

  42. S. Cabani, V. Mollica, L. Lepori, and S. T. Lobo,J. Phys. Chem. 81, 987, (1977).

    Google Scholar 

  43. S. Cabani, V. Mollica, and L. Lepori,J. Chem. Soc., Faraday Trans. I 74, 2667 (1978).

    Google Scholar 

  44. S. Cabani, S. T. Lobo, and E. Matteoli,J. Solution Chem. 8, 5 (1979).

    Google Scholar 

  45. S. Cabani, unpublished results.

  46. A. Cesaro, E. Russo, and V. Crescenzi,J. Phys. Chem. 80, 335 (1976).

    Google Scholar 

  47. Chemical Abstracts Index Guide, Am. Chem. Soc., Appendix IV (1977).

  48. A. O. Christie and D. J. Crisp,J. Appl. Chem. 17, 11 (1967).

    Google Scholar 

  49. F. E. Condon, R. T. Reece, D. G. Shapiro, D. C. Thakkar, and T. Briks Goldstein,J. Chem. Soc., Perkin II, 1112 (1974).

    Google Scholar 

  50. G. Conti, P. Gianni, E. Matteoli, and M. Mengheri,Chim. Ind. (Milan),58, 225 (1976).

    Google Scholar 

  51. B. E. Conway and L. H. Laliberté inHydrogen-Bonded Solvent Systems, A. K. Covington and P. Jones, eds., (Taylor and Francis, London, 1968), p. 139.

    Google Scholar 

  52. J. M. Corkill, J. F. Goodman, and T. Walker,Trans. Faraday. Soc. 63, 768 (1967).

    Google Scholar 

  53. J. M. Corkill, J. F. Goodman, and J. R. Tate,Trans. Faraday Soc. 65, 1742 (1969).

    Google Scholar 

  54. J. D. Cox and G. Pilcher, inThermochemistry of Organic and Organometallic Compounds (Academic Press, London, 1970).

    Google Scholar 

  55. J. Daniel and E. J. Cohn,J. Amer. Chem. Soc. 58, 415 (1936).

    Google Scholar 

  56. G. Della Gatta, Private communication.

  57. P. P. DeLuca and T. V. Rebagay,J. Phys. Chem. 79, 2493 (1975).

    Google Scholar 

  58. N. C. Deno and H. E. Berkheimer,J. Chem. Eng. Data 5, 1 (1960).

    Google Scholar 

  59. J. E. Esnoyers and F. M. Ichhaporia,Can. J. Chem. 47, 4639 (1969).

    Google Scholar 

  60. J. E. Desnoyers, R. Pagé, G. Perron, J.-L. Fortier, P.-A. Leduc, and R. F. Platford,Can. J. Chem. 51, 2129 (1973).

    Google Scholar 

  61. C. de Visser, G. Perron, and J. E. Desnoyers,Can. J. Chem. 55, 856 (1977).

    Google Scholar 

  62. C. de Visser, G. Perron, J. E. Desnoyers, W. J. M. Heuvelsland, and G. Somsen,J. Chem. Eng. Data 22, 74 (1977).

    Google Scholar 

  63. C. de Visser, P. Pel, and G. Somsen,J. Solution Chem. 6, 571 (1977).

    Google Scholar 

  64. C. de Visser, W. J. M. Heuvelsland, L. A. Dunn, and G. Somsen,J. Chem. Soc., Faraday Trans. I 74, 1159 (1978).

    Google Scholar 

  65. G. Dipaola and B. Belleau,Can. J. Chem. 55, 3825 (1977).

    Google Scholar 

  66. R. R. Dreisbach,Advan. Chem. Ser. No. 15 (1955), No. 22 (1955), No. 29 (1961).

  67. J. T. Edsall,J. Am. Chem. Soc. 57, 1506 (1935).

    Google Scholar 

  68. J. T. Edward,J. Chem. Educ. 47, 261 (1970).

    Google Scholar 

  69. J. T. Edward, P. G. Farrell, and F. Shahidi,J. Chem. Soc., Faraday Trans. I 73, 705 (1977).

    Google Scholar 

  70. O. Enea, P. P. Singh, and L. G. Hepler,J. Solution Chem. 6, 719 (1977).

    Google Scholar 

  71. O. Enea, C. Jolicoeur, and L. G. Hepler,Can. J. Chem. 58, 704 (1980).

    Google Scholar 

  72. F. Franks and H. T. Smith,Trans. Faraday Soc. 64, 2962 (1968).

    Google Scholar 

  73. F. Franks and B. Watson,Trans. Faraday Soc. 65, 2339 (1969).

    Google Scholar 

  74. F. Franks, M. A. J. Quickenden, D. S. Reid, and B. Watson,Trans. Faraday Soc. 66, 582 (1970).

    Google Scholar 

  75. F. Franks, J. R. Ravenhill, and D. S. Reid,J. Solution Chem. 1, 3 (1972).

    Google Scholar 

  76. M. E. Friedman and H. A. Scheraga,J. Phys. Chem. 69, 3795 (1965).

    Google Scholar 

  77. S. Friedman, A. Caille, and H. Daoust,Macromolecules 3, 700 (1970).

    Google Scholar 

  78. J. E. Garrod and T. M. Herrington,J. Phys. Chem. 74, 363 (1970).

    Google Scholar 

  79. A. R. Giaquinto, R. E. Lindstrom, J. Swarbrick, and A. LoSurdo,J. Solution Chem. 6, 687 (1977).

    Google Scholar 

  80. S. J. Gill, N. F. Nichols, and I. Wadsö,J. Chem. Thermodyn. 8, 445 (1976).

    Google Scholar 

  81. P. Gross, J. C. Rintelen, and J. H. Saylor,J. Phys. Chem. 43, 197 (1939).

    Google Scholar 

  82. F. T. Gucker, Jr., and F. D. Ayres,J. Am. Chem. Soc. 59, 447 (1937).

    Google Scholar 

  83. F. T. Gucker, Jr., and F. D. Ayres,J. Am. Chem. Soc. 59, 2152 (1937).

    Google Scholar 

  84. F. T. Gucker, Jr., and T. W. Allen,J. Am. Chem. Soc. 64, 191 (1942).

    Google Scholar 

  85. J. P. Guthrie,Can. J. Chem. 55, 3700 (1977).

    Google Scholar 

  86. S. D. Hamann and S. C. Lim,Aust. J. Chem. 7, 329 (1954).

    Google Scholar 

  87. S. D. Hamann and M. Linton,J. Chem. Soc., Faraday Trans. I 70, 2239 (1974).

    Google Scholar 

  88. D. Hamilton and R. H. Stokes,J. Solution Chem. 1, 213 (1972).

    Google Scholar 

  89. S. Harada, T. Nakajima, T. Komatsu, and T. Nakagawa,J. Solution Chem. 7, 463 (1978).

    Google Scholar 

  90. S. Harada and T. Nakagawa,J. Solution Chem. 8, 267 (1979).

    Google Scholar 

  91. T. T. Herskovits and T. M. Kelly,J. Phys. Chem. 77, 381 (1973).

    Google Scholar 

  92. D. J. T. Hill and L. R. White,Aust. J. Chem. 27, 1905 (1974).

    Google Scholar 

  93. J. Hine and P. K. Mookerjee,J. Org. Chem. 40, 292 (1975).

    Google Scholar 

  94. H. Høiland,Acta Chem. Scand. A-28, 699 (1974).

    Google Scholar 

  95. H. Høiland and E. Vikingstad,J. Chem. Soc. Faraday Trans. I 71, 2007 (1975).

    Google Scholar 

  96. H. Høiland,J. Chem. Soc. Faraday Trans. I 71, 797 (1975).

    Google Scholar 

  97. H. Høiland and E. Vikingstad,Acta Chem. Scand. A-30, 182 (1976).

    Google Scholar 

  98. H. Høiland and H. Holvik,J. Solution Chem. 7, 587 (1978).

    Google Scholar 

  99. H. Hølland and E. A. Moelwyn-Hughes,Trans. Faraday Soc. 52, 297 (1956).

    Google Scholar 

  100. H. P. Hopkins, Jr., W. C. Duer, and F. J. Millero,J. Solution Chem. 5, 263 (1976

    Google Scholar 

  101. P. B. Howard and I. Wadsö,Acta Chem. Scand. 24, 145 (1970).

    Google Scholar 

  102. A. Indelli,Ann. Chim. (Roma) 53, 605 (1963).

    Google Scholar 

  103. C. Jolicoeur, P. Picker, and G. Perron,Can. J. Chem. 53, 3634 (1975).

    Google Scholar 

  104. C. Jolicoeur and G. Lacroix,Can. J. Chem. 54, 624 (1976).

    Google Scholar 

  105. C. Jolicoeur, Private communication.

  106. M. V. Kaulgud and K. J. Patill,J. Phys. Chem. 78, 714 (1974).

    Google Scholar 

  107. M. V. Kaulgud and K. J. Patill,J. Phys. Chem. 80, 138 (1976).

    Google Scholar 

  108. F. Kawaizumi, T. Noguchi, and Y. Miyahara,Bull. Chem. Soc. Japan 50, 1687 (1977).

    Google Scholar 

  109. M. V. Kilday,J. Res. Natl. Bur. Stand. 83, 347, 529, 539, 547 (1978).

    Google Scholar 

  110. E. J. King,J. Phys. Chem. 73, 1220 (1969).

    Google Scholar 

  111. O. Kiyohara, G. Perron, and J. E. Desnoyers,Can. J. Chem. 53, 2591 (1975).

    Google Scholar 

  112. O. Kiyohara, G. Perron, and J. E. Desnoyers,Can. J. Chem. 53, 3263 (1975).

    Google Scholar 

  113. J. Konicek and I. Wadsö,Acta Chem. Scand. 25, 1541 (1971).

    Google Scholar 

  114. K. Kusano, J. Suurkuusk, and I. Wadsö,J. Chem. Thermodyn. 5, 757 (1973).

    Google Scholar 

  115. K. Kusano, Private communication.

  116. L. H. Laliberté and B. E. Conway,J. Phys. Chem. 74, 4116 (1970).

    Google Scholar 

  117. J. Lawrence and B. E. Conway,J. Phys. Chem. 75, 2353 (1971).

    Google Scholar 

  118. L. Lepori and V. Mollica,J. Chem. Eng. Data 23, 65 (1978).

    Google Scholar 

  119. L. Lepori and V. Mollica,J. Polym. Sci. A-2 16, 1123 (1978).

    Google Scholar 

  120. C. L. Liotta, A. Abidaud, and H. P. Hopkins, Jr.,J. Am. Chem. Soc. 94, 8624 (1972).

    Google Scholar 

  121. C. L. Liotta, H. P. Hopkins, Jr., and P. T. Kasudia,J. Am. Chem. Soc. 96, 7153 (1974).

    Google Scholar 

  122. C. L. Liotta, E. M. Perdue, and H. P. Hopkins, Jr.,J. Am. Chem. Soc. 96, 7981 (1974).

    Google Scholar 

  123. L. G. Longsworth,J. Phys. Chem. 67, 689 (1963).

    Google Scholar 

  124. A. Lo Surdo, C. Shin, and F. J. Millero,J. Chem. Eng. Data 23, 197 (1978).

    Google Scholar 

  125. D. D. MacDonald, M. E. Estep, M. D. Smith, and J. B. Byne,J. Solution Chem. 3, 713 (1974).

    Google Scholar 

  126. D. MacKay and W. Y. Shin,J. Chem. Eng. Data 22, 399 (1977).

    Google Scholar 

  127. M. Manabe and M. Koda,Bull. Chem. Soc. Japan 48, 2367 (1975).

    Google Scholar 

  128. M. Manabe and M. Koda,Mem. Niihama Tech. Coll. 12, 68 (1976).

    Google Scholar 

  129. W. L. Masterton,J. Chem. Phys. 22, 1830 (1954).

    Google Scholar 

  130. J. G. Mathieson and B. E. Conway,J. Solution Chem. 4, 17 (1975).

    Google Scholar 

  131. C. McAuliffe,J. Phys. Chem. 70, 1267 (1966).

    Google Scholar 

  132. V. Mollica and L. Lepori,Chim. Ind. (Milan) 59, 877 (1977).

    Google Scholar 

  133. T. Nakajiman, T. Komatsu, and T. Nakagawa,Bull. Chem. Soc. Japan 48, 783 (1975).

    Google Scholar 

  134. K. Nakanishi and M. Kurata,Bull. Chem. Soc. Japan 33, 152 (1960).

    Google Scholar 

  135. K. Nakanishi, N. Kato, and M. Maryuama,J. Phys. Chem. 71, 814 (1967).

    Google Scholar 

  136. J. L. Neal and D. A. I. Goring,J. Phys. Chem. 74, 658 (1970).

    Google Scholar 

  137. J. L. Neal and A. D. I. Goring,J. Phys. Chem. 74, 658 (1970).

    Google Scholar 

  138. H. D. Nelson and C. L. de Ligny,Rec. Trav. Chim. 87, 528 (1968).

    Google Scholar 

  139. G. Némethy and H. A. Scheraga,J. Chem. Phys. 36, 3401 (1962).

    Google Scholar 

  140. N. Nichols and I. Wadsö,J. Chem. Thermodyn. 7, 329 (1975).

    Google Scholar 

  141. N. Nichols, R. Skold, C. Spink, and I. Wadsö,J. Chem. Thermodyn. 8, 993 (1976).

    Google Scholar 

  142. N. Nichols, R. Skold, C. Spink, J. Suurkuusk, and I. Wadsö,J. Chem. Thermodyn. 8, 1081 (1976).

    Google Scholar 

  143. M. Palma and J. P. Morel,J. Chim. Phys. 73, 643 (1976).

    Google Scholar 

  144. P. Paoletti, Private communication.

  145. G. H. Parsons, C. H. Rochester, and C. E. C. Wood,J. Chem. Soc. B 533 (1971).

  146. G. H. Parsons, C. H. Rochester, A. Rostron, and P. C. Sykes,J. Chem. Soc., Perkin Trans. II 136 (1972).

    Google Scholar 

  147. G. Perron and J. E. Desnoyers,Fluid Phase Equilibria 2, 239 (1979).

    Google Scholar 

  148. P. R. Philip, G. Perron, and J. E. Desnoyers,Can. J. Chem. 52, 1709 (1974).

    Google Scholar 

  149. P. Picker, P.-A. Leduc, P. R. Philip, and J. E. Desnoyers,J. Chem. Thermodyn. 3, 631 (1971).

    Google Scholar 

  150. A. Ray and G. Némethy,J. Chem. Eng. Data 18, 309 (1973).

    Google Scholar 

  151. R. C. Reid, J. M. Prausnitz, and T. K. Sherwood,The Properties of Gases and Liquids, 3rd ed., (McGraw-Hill, New York, 1977).

    Google Scholar 

  152. D. Richon and A. Viallard,Can. J. Chem. 54, 2584 (1976).

    Google Scholar 

  153. D. N. Rihani and L. K. Doraiswamy,Ind. Eng. Chem. Fundam. 4, 17 (1965).

    Google Scholar 

  154. C. H. Rochester and J. R. Symonds,J. Chem. Soc. Faraday Trans. I 69, 1577 (1973).

    Google Scholar 

  155. G. Roux, G. Perron, and J. E. Desnoyers,Can. J. Chem. 56, 2808 (1978).

    Google Scholar 

  156. G. Roux, G. Perron, and J. E. Desnoyers,J. Solution Chem. 7, 639 (1978).

    Google Scholar 

  157. H. Ruterjans, F. Schreiner, U. Sage, and T. Ackermann,J. Phys. Chem. 73, 986 (1969).

    Google Scholar 

  158. L. S. Sandell and D. A. I. Goring,J. Polym. Sci. A-2 9, 115 (1971).

    Google Scholar 

  159. J. Sangster, T. T. Teng, and P. Lenzi,J. Solution Chem. 5, 575 (1976).

    Google Scholar 

  160. J. H. Saylor, V. J. Baxt, and P. M. Gross,J. Am. Chem. Soc. 64, 2742 (1942).

    Google Scholar 

  161. P. Sellers and S. Sunner,Acta Chem. Scand. 16, 46 (1962).

    Google Scholar 

  162. F. Shahidi, P. G. Farrell, and J. T. Edward,J. Solution Chem. 5, 807 (1976).

    Google Scholar 

  163. F. Shahidi, P. G. Farrell, and J. T. Edward,J. Chem. Soc., Faraday Trans I 73, 715 (1977).

    Google Scholar 

  164. F. Shahidi and P. G. Farrell,J. Chem. Soc., Faraday Trans. I 74, 858 (1978).

    Google Scholar 

  165. R. Shaw,J. Chem. Eng. Data 14, 461 (1969).

    Google Scholar 

  166. R. Singer, H. Arm, and H. Daeniker,Helv. Chim. Acta 52, 2347 (1969).

    Google Scholar 

  167. R. Skold, J. Suurkuusk, and I. Wadsö,J. Chem. Thermodyn. 8, 1075 (1976).

    Google Scholar 

  168. J. H. Stern and A. Hermann,J. Phys. Chem. 72, 364 (1968).

    Google Scholar 

  169. J. H. Stern and J. T. Swearingen,J. Phys. Chem. 74, 167 (1970).

    Google Scholar 

  170. J. H. Stern and L. R. Beeninga,J. Phys. Chem. 79, 582 (1975).

    Google Scholar 

  171. R. H. Stokes,Aust. J. Chem. 28, 2109 (1975).

    Google Scholar 

  172. D. R. Stull, E. F. Westrum, Jr., and G. C. Sinke,The Chemical Thermodynamics of Organic Compounds (Wiley, New York, 1969).

    Google Scholar 

  173. S. Subramanian, D. Bala Subramanian, and J. C. Ahluwalia,J. Phys. Chem. 73, 266 (1969).

    Google Scholar 

  174. J. Szeminska, W. Zielenkiewicz, and K. L. Wierzchowski,Biophys. Chem. 10, 409 (1979).

    Google Scholar 

  175. S. Terasawa, H. Itsuki, and S. Arakawa,J. Phys. Chem. 79, 2345 (1975).

    Google Scholar 

  176. E. W. Tiepel and K. E. Gubbins,J. Phys. Chem. 76, 3044 (1972).

    Google Scholar 

  177. V. A. Vasilev, E. Y. Shevchenko, N. V. Fedyainov, and M. V. Golikov,Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Teknol. 20, 1557 (1977).

    Google Scholar 

  178. R. E. Verrall and B. E. Conway,J. Phys. Chem. 70, 3961 (1966).

    Google Scholar 

  179. I. Wadsö,Acta Chem. Scand. 23, 2061 (1969).

    Google Scholar 

  180. W. J. Wallace, C. S. Shephard, and C. Underwood,J. Chem. Eng. Data 13, 11 (1968).

    Google Scholar 

  181. R. D. Wauchope and R. Haque,Can. J. Chem. 50, 133 (1972).

    Google Scholar 

  182. W. Y. Wen, N. Takeguchi, and D. P. Wilson,J. Solution Chem. 3, 103 (1974).

    Google Scholar 

  183. E. Wilhelm, R. Battino, and R. J. Wilcock,Chem. Rev. 77, 219 (1977).

    Google Scholar 

  184. R. Wolfenden,J. Am. Chem. Soc. 98, 1987 (1976).

    Google Scholar 

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Authors and Affiliations

  1. Istituto di Chimica Fisica, Università degli Studi di Pisa, Via Risorgimento 35, 56100, Pisa, Italy

    Sergio Cabani, Paolo Gianni & Vincenzo Mollica

  2. Istituto di Chimica Quantistica ed Energetica Molecolare del C.N.R., Via Risorgimento 35, Pisa, Italy

    Luciano Lepori

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  1. Sergio Cabani
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  2. Paolo Gianni
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  3. Vincenzo Mollica
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  4. Luciano Lepori
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Cabani, S., Gianni, P., Mollica, V. et al. Group contributions to the thermodynamic properties of non-ionic organic solutes in dilute aqueous solution. J Solution Chem 10, 563–595 (1981). https://doi.org/10.1007/BF00646936

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