Skip to main content
Log in

Diffusion coefficients of the ternary system water-tetrabutylammonium bromide-potassium bromide as a function of tetrabutylammonium bromide concentration

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Sets of four diffusion coefficients were obtained for the water-tetrabutylammonium bromide-potassium bromide system at 25°C as a function of tetrabutylammonium bromide concentration with the mean concentration of potassiumbromide fixed at 0.1 mole-liter−1. The experiments were performed at tetrabutylammonium bromide concentrations of 0.075, 0.15, 0.3, and 0.45 mole-liter−1. The results are compared with the binary diffusion coefficients of these components and also with the calculated diffusion coefficients using the first approximation theory.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. G. Miller,J. Phys. Chem. 70, 2639 (1966);71, 616 (1967).

    Google Scholar 

  2. M. J. Pikal,—ibid.75, 3124 (1971).

    Google Scholar 

  3. D. G. Miller and M. J. Pikal,J. Solution Chem. 1, 111 (1972).

    Google Scholar 

  4. H. Kim, G. Reinfelds, and L. J. Gosting,J. Phys. Chem. 77, 934 (1973).

    Google Scholar 

  5. L. A. Woolf, D. G. Miller, and L. J. Gosting,J. Am. Chem. Soc. 84, 317 (1962).

    Google Scholar 

  6. R. P. Wendt,J. Phys. Chem. 66, 1740 (1962).

    Google Scholar 

  7. G. Reinfelds and L. J. Gosting,ibid.,68, 2464 (1964).

    Google Scholar 

  8. L. J. Gosting,Advan. Protein Chem. 11, 536 (1956).

    Google Scholar 

  9. H. Kim, A. Revzin, and L. J. Gosting,J. Phys. Chem. 77, 2567 (1973).

    Google Scholar 

  10. C. N. Pepela, B. J. Steel, and P. J. Dunlop,J. Am. Chem. Soc. 92, 6743 (1970).

    Google Scholar 

  11. R. A. Robinson and R. H. Stokes,Electrolyte Solutions, 2nd rev.ed. (Butterworths, London, 1965).

    Google Scholar 

  12. J. E. Desnoyers and G. Perron,J. Solutions Chem. 1, 199 (1972).

    Google Scholar 

  13. W.-Y. Wen and S. Saito,J. Phys. Chem. 68, 2639 (1964).

    Google Scholar 

  14. H. Kim and G. Reinfelds,J. Solution Chem. 2, 477 (1973).

    Google Scholar 

  15. B. J. Steel, J. M. Stokes, and R. H. Stokes,J. Phys. Chem. 62, 1514 (1958).

    Google Scholar 

  16. J. H. Wang,J. Am. Chem. Soc. 76, 6755 (1954).

    Google Scholar 

  17. A. Biancheria and G. Kegeles,ibid.,79, 5908 (1957).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kim, H. Diffusion coefficients of the ternary system water-tetrabutylammonium bromide-potassium bromide as a function of tetrabutylammonium bromide concentration. J Solution Chem 3, 149–159 (1974). https://doi.org/10.1007/BF00646884

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00646884

Key Words

Navigation