Abstract
Excess volumes of binary mixtures of water with methanol, ethanol and 1-propanol were obtained from density measurements at 5 degree intervals from 15 to 35°C over the entire composition range. Excess thermal expansion coefficients, partial molar excess volumes, and expansibilities at 25°C were derived from the results. The significance of these values is discussed in relation to hypothesized structural changes in the mixtures.
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Benson, G.C., Kiyohara, O. Thermodynamics of aqueous mixtures of nonelectrolytes. I. Excess volumes of water-n-alcohol mixtures at several temperatures. J Solution Chem 9, 791–804 (1980). https://doi.org/10.1007/BF00646798
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DOI: https://doi.org/10.1007/BF00646798