Abstract
Enthalpies of solution of tetramethylammonium chloride in H2O+acetone, H2O+DMSO, and H2O+2,2,2-trifluoroethanol (TFE) are reported. The enthalpies of solution for the frist two solvent systems are positive for all compositions investigated, whereas for the H2O+TFE systemsΔHs becomes large and negative as the mole fraction of TFE is increased past 0.2. The enthalpy-of-solution data are rationalized on the basis of solvent structural effects and solvation.
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Estep, M.E., Macdonald, D.D. & Hyne, J.B. Enthalpies of solution of tetramethyl-ammonium chloride in aqueous-organic binary solvent systems. J Solution Chem 6, 129–134 (1977). https://doi.org/10.1007/BF00646734
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DOI: https://doi.org/10.1007/BF00646734