Abstract
A recently developed calorimetric method has been employed to estimate the thermodynamic functions for transfer of 1-propanol, 1-butanol, 1-pentanol, 1-hexanol and 1-heptanol from n-octane to water at 25°C. A linear correlation for ΔG ot as a function of the number of carbon atoms of the alchohol molecule has been found but for ΔH ot and ΔS ot the dependence gave well defined minima.
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References
R. De Lisi, M. Goffredi, and V. Turco Liveri,J. C. S. Chem. Comm. 9, 380 (1980).
J. M. Geest and M. R. Cannon,Ind. Eng. Chem. Anal. Ed.18, 611 (1946).
William J. Dunn and Svante Wald,Acta Chem. Scand. B32, 536 (1978).
G. L. Starobinets, E. M. Rakhman'ko, and S. M. Leshchev,Zh. Fiz. Khim. 52, 2284 (1978).
A. Leo, C. Hansch, and D. Elkins,Chem. Rev. 71, 525 (1971).
Michael H. Abraham,J. Am. Chem. Soc. 101, 5477 (1979).
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Goffredi, M., Liveri, V.T. Thermodynamics of transfer of non-ionic solutes between immiscible liquid phases. I. Transfer of normal alcohols fromn-octane to water at 25°C. J Solution Chem 10, 693–698 (1981). https://doi.org/10.1007/BF00646720
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DOI: https://doi.org/10.1007/BF00646720