Abstract
A recently developed calorimetric method has been employed to estimate the thermodynamic functions for transfer of 1-propanol, 1-butanol, 1-pentanol, 1-hexanol and 1-heptanol from n-octane to water at 25°C. A linear correlation for ΔG ot as a function of the number of carbon atoms of the alchohol molecule has been found but for ΔH ot and ΔS ot the dependence gave well defined minima.
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Goffredi, M., Liveri, V.T. Thermodynamics of transfer of non-ionic solutes between immiscible liquid phases. I. Transfer of normal alcohols fromn-octane to water at 25°C. J Solution Chem 10, 693–698 (1981). https://doi.org/10.1007/BF00646720
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DOI: https://doi.org/10.1007/BF00646720